KEGG   ENZYME: 2.5.1.34Help
Entry
EC 2.5.1.34                 Enzyme                                 

Name 4-dimethylallyltryptophan synthase;
dimethylallylpyrophosphate:L-tryptophan dimethylallyltransferase;
dimethylallyltryptophan synthetase;
dimethylallylpyrophosphate:tryptophan dimethylallyl transferase;
DMAT synthetase;
4-(gamma,gamma-dimethylallyl)tryptophan synthase;
tryptophan dimethylallyltransferase
Class Transferases;
Transferring alkyl or aryl groups, other than methyl groups;
Transferring alkyl or aryl groups, other than methyl groups (only
sub-subclass identified to date)
BRITE hierarchy
Sysname dimethylallyl-diphosphate:L-tryptophan 4-dimethylallyltransferase
Reaction(IUBMB) dimethylallyl diphosphate + L-tryptophan = diphosphate +
4-(3-methylbut-2-enyl)-L-tryptophan [RN:R01657]
Reaction(KEGG) R01657;
(other) R02943
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Substrate dimethylallyl diphosphate [CPD:C00235];
L-tryptophan [CPD:C00078]
Product diphosphate [CPD:C00013];
4-(3-methylbut-2-enyl)-L-tryptophan [CPD:C04290]
Reference
  Authors
  Title



  Journal
  Organism
1  [PMID:999297]
Lee SL, Floss HG, Heinstein P.
Purification and properties of
dimethylallylpyrophosphate:tryptopharm dimethylallyl transferase,
the first enzyme of ergot alkaloid biosynthesis in Claviceps. sp. SD
58.
Arch. Biochem. Biophys. 177 (1976) 84-94.
Claviceps. sp.
Other DBs ExplorEnz - The Enzyme Database: 2.5.1.34
IUBMB Enzyme Nomenclature: 2.5.1.34
ExPASy - ENZYME nomenclature database: 2.5.1.34
BRENDA, the Enzyme Database: 2.5.1.34
CAS: 55127-01-0

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