KEGG   COMPOUND: C15975
Entry
C15975                      Compound                               

Name
[Dihydrolipoyllysine-residue (2-methylpropanoyl)transferase] S-(3-methylbutanoyl)dihydrolipoyllysine;
S-(3-Methylbutanoyl)-dihydrolipoamide-E
Formula
C13H24NO2S2R
Structure
Comment
Generic compound in reaction hierarchy
The 3-methylbutanoyl thioester of the reduced lipoyllysine residue in dihydrolipoyllysine-residue (2-methylpropanoyl)transferase [EC:2.3.1.168].
Reaction
Pathway
map00280  Valine, leucine and isoleucine degradation
map01100  Metabolic pathways
Module
M00036  Leucine degradation, leucine => acetoacetate + acetyl-CoA
Enzyme
1.2.4.4         2.3.1.168
Other DBs
PubChem: 47205288
ChEBI: 80221
LinkDB
KCF data

ATOM        19
            1   C1c C    17.8461  -16.8441
            2   C1b C    19.0385  -17.5455
            3   C1b C    16.6538  -17.5455
            4   S1a S    17.8461  -15.4413
            5   C1b C    20.2308  -16.8441
            6   C1b C    15.4614  -16.8441
            7   C1b C    21.4933  -17.5455
            8   S2a S    15.4614  -15.4413
            9   C1b C    22.6856  -16.8441
            10  C5a C    23.8780  -17.5455
            11  O5a O    23.8780  -18.9482
            12  N1b N    25.2106  -16.8441
            13  R   R    26.6133  -16.8441
            14  C5a C    14.2691  -14.7399
            15  C1b C    13.0768  -15.4413
            16  C1c C    11.8844  -14.7399
            17  O5a O    14.2691  -13.3372
            18  C1a C    10.6921  -15.4413
            19  C1a C    11.8844  -13.3372
BOND        18
            1     1   2 1 #Down
            2     1   3 1
            3     1   4 1
            4     2   5 1
            5     3   6 1
            6     5   7 1
            7     6   8 1
            8     7   9 1
            9     9  10 1
            10   10  11 2
            11   10  12 1
            12   12  13 1
            13    8  14 1
            14   14  15 1
            15   15  16 1
            16   14  17 2
            17   16  18 1
            18   16  19 1

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