| Entry |
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| Name |
(hydroxymethyl)phosphonate dioxygenase;
phnZ1 (gene name)
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| Class |
Oxidoreductases;
Acting on single donors with incorporation of molecular oxygen (oxygenases);
With incorporation of two atoms of oxygen
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| Sysname |
(hydroxymethyl)phosphonate:oxygen 1-oxidoreductase (formate-forming)
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| Reaction(IUBMB) |
(hydroxymethyl)phosphonate + O2 = formate + phosphate [RN: R12451]
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| Reaction(KEGG) |
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| Substrate |
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| Product |
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| Comment |
Requires iron(II). The enzyme, characterized from the marine bacterium Gimesia maris, participates in a methylphosphonate degradation pathway. It also has the activity of EC 1.13.11.78, (2-amino-1-hydroxyethyl)phosphonate dioxygenase (glycine-forming).
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| History |
EC 1.13.11.89 created 2019
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| Pathway |
| ec00440 | Phosphonate and phosphinate metabolism |
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| Orthology |
| K05915 | (hydroxymethyl)phosphonate/2-amino-1-hydroxyethylphosphonate dioxygenase |
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| Genes |
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| Reference |
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| Authors |
Gama SR, Vogt M, Kalina T, Hupp K, Hammerschmidt F, Pallitsch K, Zechel DL |
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| Title |
An Oxidative Pathway for Microbial Utilization of Methylphosphonic Acid as a Phosphate Source. |
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| Journal |
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| Sequence |
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| Other DBs |
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| LinkDB |
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