KEGG ENZYME: 1.3.99.25

ENZYME: 1.3.99.25

Entry

EC 1.3.99.25                Enzyme

Name

carvone reductase

Class

Oxidoreductases;
Acting on the CH-CH group of donors;
With unknown physiological acceptors

Sysname

(+)-dihydrocarvone:acceptor 1,6-oxidoreductase

Reaction(IUBMB)

(1) (+)-dihydrocarvone + acceptor = (-)-carvone + reduced acceptor [RN:R06373];
(2) (-)-isodihydrocarvone + acceptor = (+)-carvone + reduced acceptor [RN:R06372]

Reaction(KEGG)

R06372 R06373

Substrate

(+)-dihydrocarvone;
acceptor [CPD:C00028];
(-)-isodihydrocarvone

Product

(-)-carvone [CPD:C01767];
reduced acceptor [CPD:C00030];
(+)-carvone [CPD:C11383]

Comment

This enzyme participates in the carveol and dihydrocarveol degradation pathway of the Gram-positive bacterium Rhodococcus erythropolis DCL14. The enzyme has not been purified, and requires an unknown cofactor, which is different from NAD+, NADP+ or a flavin.

History

EC 1.3.99.25 created 2008

Pathway

ec00903

Limonene and pinene degradation

ec01110

Biosynthesis of secondary metabolites

Reference

1 [PMID:10832640]

Authors

van der Werf MJ, Boot AM

Title