Entry |
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Name |
5,10-dihydrophenazine-1-carboxylate 9-dimethylallyltransferase;
PpzP;
dihydrophenazine-1-carboxylate dimethylallyltransferase;
5,10-dihydrophenazine 1-carboxylate dimethylallyltransferase
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Class |
Transferases;
Transferring alkyl or aryl groups, other than methyl groups;
Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
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Sysname |
dimethylallyl diphosphate:5,10-dihydrophenazine-1-carboxylate 9-dimethylallyltransferase
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Reaction(IUBMB) |
dimethylallyl diphosphate + 5,10-dihydrophenazine-1-carboxylate = diphosphate + 9-(dimethylallyl)-5,10-dihydrophenazine-1-carboxylate [RN: R10966]
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Reaction(KEGG) |
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Substrate |
dimethylallyl diphosphate [CPD: C00235];
5,10-dihydrophenazine-1-carboxylate [CPD: C20981]
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Product |
diphosphate [CPD: C00013];
9-(dimethylallyl)-5,10-dihydrophenazine-1-carboxylate [CPD: C20982]
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Comment |
The enzyme is involved in the biosynthesis of prenylated phenazines by the bacterium Streptomyces anulatus. It is specific for both dimethylallyl diphosphate and 5,10-dihydrophenazine-1-carboxylate.
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History |
EC 2.5.1.121 created 2014
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Pathway |
ec01110 | Biosynthesis of secondary metabolites |
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Orthology |
K21338 | 5,10-dihydrophenazine-1-carboxylate 9-dimethylallyltransferase |
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Reference |
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Authors |
Saleh O, Gust B, Boll B, Fiedler HP, Heide L |
Title |
Aromatic prenylation in phenazine biosynthesis: dihydrophenazine-1-carboxylate dimethylallyltransferase from Streptomyces anulatus. |
Journal |
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Sequence |
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Other DBs |
ExPASy - ENZYME nomenclature database: | 2.5.1.121 |
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LinkDB |
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