| Entry |
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| Name |
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| Class |
Isomerases;
Intramolecular oxidoreductases;
Other intramolecular oxidoreductases
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| Sysname |
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate isomerase (cyclizing)
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| Reaction(IUBMB) |
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate = (15Z)-12-oxophyto-10,15-dienoate [RN: R03402]
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| Reaction(KEGG) |
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| Substrate |
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate [CPD: C04672]
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| Product |
(15Z)-12-oxophyto-10,15-dienoate [CPD: C01226]
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| Comment |
Allene oxides formed by the action of EC 4.2.1.92 hydroperoxide dehydratase, are converted into cyclopentenone derivatives.
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| History |
EC 5.3.99.6 created 1992
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| Pathway |
| ec00592 | alpha-Linolenic acid metabolism |
| ec01110 | Biosynthesis of secondary metabolites |
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| Orthology |
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| Genes |
| ATH: | AT1G13280(AOC4) AT3G25760(AOC1) AT3G25770(AOC2) AT3G25780(AOC3) |
| ALY: | 9311345 9311346 9311347 9326060 |
| CRB: | 17885022 17885176 17885278 17897897 |
| CSAT: | 104710341 104710342 104710345 104710348 104714963 104739983 104755611 104772239 104779760 104779762 104779776 104790190 104790191 104790194 |
| EUS: | EUTSA_v10004810mg EUTSA_v10004824mg EUTSA_v10008630mg |
| BRP: | 103836113 103839361 103839364 103875352 103875422 |
| BNA: | 106350927 106352449 106362074 106409047 106416449 106416621 106437957 106443552 125577176 125589999 |
| BOE: | 106304493 106305039 106312059 106313826 106316858 |
| RSZ: | 108822889 108825544 108827249 108853876 |
| THJ: | 104805247 104824037 104825709 |
| CIT: | 102622584 102622874 102623756 |
| CIC: | CICLE_v10012528mg CICLE_v10012552mg CICLE_v10032510mg |
| MINC: | 123197606 123213654 123215880 |
| TCC: | 18602090 18607697 18610534 |
| GRA: | 105764558 105790379 105790380 105790381 128031965 |
| GHI: | 107916767 107916775 107916790 107946443 121202816 121204899 121204900 121204901 121220211 |
| GAB: | 108469180 108469715 108469716 108469717 108480614 |
| HSYR: | 120129720 120172420 120181137 120188875 120193331 120209033 120215996 |
| DZI: | 111287431 111288129 111313644 111318404 |
| GMX: | 100775373(AOC1) 100795498(AOC3) 100800036 100803536(AOC5) 100803666(AOC4) 100805194(AOC6) |
| GSJ: | 114382466 114385835 114394448 114400423 114413802 114423435 |
| PVU: | PHAVU_003G111500g PHAVU_004G072000g PHAVU_008G020200g |
| VRA: | 106758100 106774129 106777743 |
| VAR: | 108327936 108335689 108344735 |
| VUN: | 114174359 114182442 114183281 |
| VUM: | 124821977 124848294 124848879 |
| CCAJ: | 109789811 109802291 109807875 |
| APRC: | 113862936 113867663 113868950 |
| MTR: | 11433162 25492710 25495597 25495598 25499834 |
| TPRA: | 123893022 123911651 |
| PSAT: | 127095469 127119150 127128378 127128380 |
| VVO: | 131611321 131630556 131630557 131647383 131649737 |
| LJA: | 130732628 130737566 130739583 |
| ADU: | 107471452 107472554 107473823 107486497 107491290 |
| AIP: | 107614735 107623642 107635545 107643776 |
| AHF: | 112716691 112728907 112740621 112744732 112750538 112777788 112783372 112798019 112802681 |
| LANG: | 109326575 109335008 109347405 109353304 109354114 109355798 109359238 |
| PCIN: | 129293391 129311134 |
| QSA: | O6P43_004321 O6P43_004322 O6P43_009264 O6P43_025678 |
| FVE: | 101294384 101305363 101311343 |
| RCN: | 112180867 112188761 112197345 |
| PMUM: | 103329664 103341439 |
| PAVI: | 110748489 110757131 110758230 110759708 |
| PDUL: | 117621021 117627108 |
| MDM: | 103402724 103411240 103423658 103433988 103451672 |
| MSYL: | 126594237 126594851 126608051 126620093 126634029 |
| PXB: | 103929185 103947146 103947801 |
| ZJU: | 107416556 107416558 107429485 |
| CSAV: | 115699327 115700991 115701324 |
| CMAX: | 111472108 111486971 111489456 |
| CMOS: | 111445098 111445257 111458193 |
| CPEP: | 111784509 111788683 111808599 |
| MEAN: | 126671745 126679513 |
| JCU: | 105638701(AOC) 105641985 |
| HBR: | 110642011 110642243 110643837 110656018 |
| MESC: | 110600311 110609890 110631034 |
| POP: | 18107399 7483932 7494544 |
| PEU: | 105110920 105123352 105123721 |
| PALZ: | 118029685 118056003 |
| JRE: | 108987084 109002736 109002750 |
| CILL: | 122302791 122302792 122308089 122309351 |
| CAVE: | 132181129 132181536 132182579 132182580 |
| QSU: | 112015604 112015605 112015607 112025648 136062158 |
| QLO: | 115975827 115975828 115975829 115988347 |
| TWL: | 119992308 120001774 120016275 |
| NTA: | 107767576 107768393(aoc) |
| INI: | 109151137 109168506(AOC) |
| SIND: | 105162178 105177957 |
| EGT: | 105965943 105966076 105974425 |
| SSPL: | 121749627 121767287 121769720 121787779 |
| SMIL: | 131004472 131023928 131024642 |
| APAN: | 127242326 127248592 127264233 |
| HAN: | 110889417 110902211 110908787 110911893 |
| CCAV: | 112513300 112513449 112515446 |
| DCR: | 108193732 108216213 108220215 |
| CSIN: | 114285638 114285648 114307969 |
| RVL: | 131297961 131300839 131304611 131309346 |
| AEW: | 130768173 130768765 130778102 |
| CQI: | 110691262 110719970 110724846 110728173 110733354 110733355 |
| ATRI: | 130802313 130803830 |
| MING: | 122075712 122078647 |
| PSOM: | 113275629 113282007 |
| TAES: | 123128593 123138464 123145716 |
| ZMA: | 100273356(aoc2) 542151(aoc1) |
| MFLO: | 136493996 136539586 |
| PVIR: | 120651985 120690841 |
| MUS: | 103978400 103979699 103980244 103981102 |
| ZOF: | 121969756 121974885 122012396 122016867 |
| MSIN: | 131234991 131237582 |
| NCOL: | 116249215 116263940 116263969 116264569 116264876 |
| SMO: | SELMODRAFT_124720 SELMODRAFT_91887 |
| PPP: | 112274177 112280616 112281962 112282144 112284572 |
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| Reference |
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| Authors |
Hamberg M. |
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| Title |
Biosynthesis of 12-oxo-10,15(Z)-phytodienoic acid: identification of an allene oxide cyclase. |
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| Journal |
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| Other DBs |
| ExplorEnz - The Enzyme Database: | 5.3.99.6 |
| ExPASy - ENZYME nomenclature database: | 5.3.99.6 |
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| LinkDB |
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