KEGG   COMPOUND: C15975
Entry
C15975                      Compound                               
Name
[Dihydrolipoyllysine-residue (2-methylpropanoyl)transferase] S-(3-methylbutanoyl)dihydrolipoyllysine;
S-(3-Methylbutanoyl)-dihydrolipoamide-E
Formula
C13H24NO2S2R
Structure
Comment
Generic compound in reaction hierarchy
The 3-methylbutanoyl thioester of the reduced lipoyllysine residue in dihydrolipoyllysine-residue (2-methylpropanoyl)transferase [EC:2.3.1.168].
Reaction
R01702 R04097 R07602
Pathway
map00280  Valine, leucine and isoleucine degradation
map00785  Lipoic acid metabolism
map01100  Metabolic pathways
Module
M00036  Leucine degradation, leucine => acetoacetate + acetyl-CoA
Enzyme
1.2.4.4         2.3.1.168
Other DBs
PubChem: 47205288
ChEBI: 80221
LinkDB
KCF data

ATOM        19
            1   C1c C    17.8461  -16.8441
            2   C1b C    19.0385  -17.5455
            3   C1b C    16.6538  -17.5455
            4   S1a S    17.8461  -15.4413
            5   C1b C    20.2308  -16.8441
            6   C1b C    15.4614  -16.8441
            7   C1b C    21.4933  -17.5455
            8   S2a S    15.4614  -15.4413
            9   C1b C    22.6856  -16.8441
            10  C5a C    23.8780  -17.5455
            11  O5a O    23.8780  -18.9482
            12  N1b N    25.2106  -16.8441
            13  R   R    26.6133  -16.8441
            14  C5a C    14.2691  -14.7399
            15  C1b C    13.0768  -15.4413
            16  C1c C    11.8844  -14.7399
            17  O5a O    14.2691  -13.3372
            18  C1a C    10.6921  -15.4413
            19  C1a C    11.8844  -13.3372
BOND        18
            1     1   2 1 #Down
            2     1   3 1
            3     1   4 1
            4     2   5 1
            5     3   6 1
            6     5   7 1
            7     6   8 1
            8     7   9 1
            9     9  10 1
            10   10  11 2
            11   10  12 1
            12   12  13 1
            13    8  14 1
            14   14  15 1
            15   15  16 1
            16   14  17 2
            17   16  18 1
            18   16  19 1

» Japanese version

KEGG   COMPOUND: C15977
Entry
C15977                      Compound                               
Name
[Dihydrolipoyllysine-residue (2-methylpropanoyl)transferase] S-(2-methylpropanoyl)dihydrolipoyllysine;
S-(2-Methylpropanoyl)-dihydrolipoamide-E;
S-(2-Methylpropionyl)-dihydrolipoamide-E;
Enzyme N6-(S-[2-methylpropanoyl]dihydrolipoyl)lysine
Formula
C12H22NO2S2R
Structure
Comment
Generic compound in reaction hierarchy
The 2-methylpropanoyl thioester of the reduced lipoyllysine residue in dihydrolipoyllysine-residue (2-methylpropanoyl)transferase [EC:2.3.1.168].
Reaction
R01701 R02662 R07600
Pathway
map00280  Valine, leucine and isoleucine degradation
map00785  Lipoic acid metabolism
map01100  Metabolic pathways
Enzyme
1.2.4.4         2.3.1.168
Other DBs
PubChem: 47205290
ChEBI: 80222
LinkDB
KCF data

ATOM        18
            1   C1c C    17.2261  -16.8741
            2   C1b C    18.4164  -17.5743
            3   C1b C    16.0359  -17.5743
            4   S1a S    17.2261  -15.4738
            5   C1b C    19.6065  -16.8741
            6   C1b C    14.8457  -16.8741
            7   C1b C    20.8668  -17.5743
            8   S2a S    14.8457  -15.4738
            9   C1b C    22.0569  -16.8741
            10  C5a C    23.2472  -17.5743
            11  O5a O    23.2472  -18.9745
            12  N1b N    24.5774  -16.8741
            13  R   R    25.9776  -16.8741
            14  C5a C    13.6555  -14.7737
            15  C1c C    12.4653  -15.4738
            16  C1a C    11.2750  -14.7737
            17  O5a O    13.6555  -13.3735
            18  C1a C    12.4650  -16.8999
BOND        17
            1     1   2 1 #Down
            2     1   3 1
            3     1   4 1
            4     2   5 1
            5     3   6 1
            6     5   7 1
            7     6   8 1
            8     7   9 1
            9     9  10 1
            10   10  11 2
            11   10  12 1
            12   12  13 1
            13    8  14 1
            14   14  15 1
            15   15  16 1
            16   14  17 2
            17   15  18 1

» Japanese version

KEGG   COMPOUND: C15979
Entry
C15979                      Compound                               
Name
[Dihydrolipoyllysine-residue (2-methylpropanoyl)transferase] S-(2-methylbutanoyl)dihydrolipoyllysine;
S-(2-Methylbutanoyl)-dihydrolipoamide-E
Formula
C13H24NO2S2R
Structure
Comment
Generic compound in reaction hierarchy
The 2-methylbutanoyl thioester of the reduced lipoyllysine residue in dihydrolipoyllysine-residue (2-methylpropanoyl)transferase [EC:2.3.1.168].
Reaction
R03174 R04225 R07604
Pathway
map00280  Valine, leucine and isoleucine degradation
map00785  Lipoic acid metabolism
map01100  Metabolic pathways
Enzyme
1.2.4.4         2.3.1.168
Other DBs
PubChem: 47205292
ChEBI: 80224
LinkDB
KCF data

ATOM        19
            1   C1c C    17.8116  -16.8911
            2   C1b C    19.0028  -17.5918
            3   C1b C    16.6205  -17.5918
            4   S1a S    17.8116  -15.4898
            5   C1b C    20.1939  -16.8911
            6   C1b C    15.4294  -16.8911
            7   C1b C    21.4551  -17.5918
            8   S2a S    15.4294  -15.4898
            9   C1b C    22.6461  -16.8911
            10  C5a C    23.8373  -17.5918
            11  O5a O    23.8373  -18.9931
            12  N1b N    25.1686  -16.8911
            13  R   R    26.5698  -16.8911
            14  C5a C    14.2383  -14.7891
            15  C1c C    13.0472  -15.4898
            16  C1b C    11.8560  -14.7891
            17  O5a O    14.2383  -13.3878
            18  C1a C    10.6650  -15.4898
            19  C1a C    13.0469  -16.9169
BOND        18
            1     1   2 1 #Down
            2     1   3 1
            3     1   4 1
            4     2   5 1
            5     3   6 1
            6     5   7 1
            7     6   8 1
            8     7   9 1
            9     9  10 1
            10   10  11 2
            11   10  12 1
            12   12  13 1
            13    8  14 1
            14   14  15 1
            15   15  16 1
            16   14  17 2
            17   16  18 1
            18   15  19 1 #Up

» Japanese version

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