KEGG Orthology (KO) [BR:ko00001]
09100 Metabolism
09109 Metabolism of terpenoids and polyketides
00902 Monoterpenoid biosynthesis
K21069 CYP9T2_3; ipsdienol synthase
09180 Brite Hierarchies
09181 Protein families: metabolism
00199 Cytochrome P450
K21069 CYP9T2_3; ipsdienol synthase
Enzymes [BR:ko01000]
1. Oxidoreductases
1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
1.14.14.31 ipsdienol synthase
K21069 CYP9T2_3; ipsdienol synthase
Cytochrome P450 [BR:ko00199]
Cytochrome P450, animal type
CYP9 family
K21069 CYP9T2_3; ipsdienol synthase
Oxidoreductases;
Acting on paired donors, with incorporation or reduction of molecular oxygen;
With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
A cytochrome P-450 heme-thiolate protein. Involved in the insect aggregation pheromone production. Isolated from the pine engraver beetle, Ips pini. A small amount of (S)-ipsdienol is also formed. In vitro it also hydroxylated (+)- and (-)-alpha-pinene, 3-carene, and (+)-limonene, but not alpha-phellandrene, (-)-beta-pinene, gamma-terpinene, or terpinolene.
History
EC 1.14.14.31 created 2015 as EC 1.14.13.207, transferred 2016 to EC 1.14.14.31
Enzymatic reactions [BR:br08201]
1. Oxidoreductase reactions
1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
1.14.14.31
R11055 Myrcene + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (R)-Ipsdienol + [Oxidized NADPH---hemoprotein reductase] + H2O