KEGG   ORTHOLOGY: K21227
Entry
K21227            Tight     KO                                     
Symbol
kedY4
Name
MIO-dependent 2-aza-L-tyrosine aminomutase [EC:5.4.3.-]
Pathway
map01059  Biosynthesis of enediyne antibiotics
map01100  Metabolic pathways
map01110  Biosynthesis of secondary metabolites
Module
M00832  Kedarcidin 2-aza-3-chloro-beta-tyrosine moiety biosynthesis, azatyrosine => 2-aza-3-chloro-beta-tyrosyl-PCP
Reaction
R11391  2-aza-L-tyrosine 2,3-aminomutase
Brite
KEGG Orthology (KO) [BR:ko00001]
 09100 Metabolism
  09109 Metabolism of terpenoids and polyketides
   01059 Biosynthesis of enediyne antibiotics
    K21227  kedY4; MIO-dependent 2-aza-L-tyrosine aminomutase
Other DBs
COG: COG2986
Genes
AG: AFV52190(kedY4)
Reference
  Authors
Huang SX, Lohman JR, Huang T, Shen B
  Title
A new member of the 4-methylideneimidazole-5-one-containing aminomutase family from the enediyne kedarcidin biosynthetic pathway.
  Journal
Proc Natl Acad Sci U S A 110:8069-74 (2013)
DOI:10.1073/pnas.1304733110
  Sequence
LinkDB

KEGG   REACTION: R11391
Entry
R11391                      Reaction                               
Name
2-aza-L-tyrosine 2,3-aminomutase
Definition
Azatyrosine <=> (R)-2-Aza-beta-tyrosine
Equation
Reaction class
RC00366  C21325_C21326
Enzyme
5.4.3.-
Pathway
rn01059  Biosynthesis of enediyne antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00832  Kedarcidin 2-aza-3-chloro-beta-tyrosine moiety biosynthesis, azatyrosine => 2-aza-3-chloro-beta-tyrosyl-PCP
Brite
Enzymatic reactions [BR:br08201]
 5. Isomerase reactions
  5.4  Intramolecular transferases
   5.4.3  Transferring amino groups
    5.4.3.-
     R11391  Azatyrosine <=> (R)-2-Aza-beta-tyrosine
Orthology
K21227  MIO-dependent 2-aza-L-tyrosine aminomutase [EC:5.4.3.-]
LinkDB

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