KEGG   REACTION: R03820
Entry
R03820                      Reaction                               
Name
Strictosidine beta-D-glucohydrolase
Definition
3-alpha(S)-Strictosidine + H2O <=> Strictosidine aglycone + D-Glucose
Equation
Reaction class
RC00049  C00031_C03470  C03309_C03470
Enzyme
Pathway
rn00901  Indole alkaloid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K12693  strictosidine beta-D-glucosidase [EC:3.2.1.105]
Other DBs
RHEA: 12920
LinkDB

KEGG   REACTION: R05844
Entry
R05844                      Reaction                               
Definition
Strictosidine aglycone <=> Dialdehyde
Equation
Comment
spontaneous(following EC3.2.1.105 or R03820 reaction)
Ref:1. J Biol Chem. 2000;275(5):3051-3056
Reaction class
RC01602  C03309_C11678
Pathway
rn00901  Indole alkaloid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
LinkDB

KEGG   REACTION: R05845
Entry
R05845                      Reaction                               
Definition
Dialdehyde + H+ <=> 4,21-Dehydrocorynantheine aldehyde + H2O
Equation
Comment
spontaneous(following EC3.2.1.105 or R03820+R05844 reaction)
Ref:1. Biochemistry 1983; 22: 3448-3452
Reaction class
RC01649  C11678_C11679
Pathway
rn00901  Indole alkaloid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
LinkDB

KEGG   REACTION: R05824
Entry
R05824                      Reaction                               
Definition
4,21-Dehydrocorynantheine aldehyde <=> 4,21-Dehydrogeissoschizine
Equation
Comment
spontaneous(following EC3.2.1.105 or R03820+R05844+R05845 reaction)
Ref:1. Biochemistry 1983; 22: 3448-3452
Reaction class
RC01605  C03677_C11679
Pathway
rn00901  Indole alkaloid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
LinkDB

KEGG   REACTION: R03860
Entry
R03860                      Reaction                               
Name
Geissoschizine:NADP+ 4,21-oxidoreductase
Definition
Geissoschizine + NADP+ <=> 4,21-Dehydrogeissoschizine + NADPH
Equation
Reaction class
RC00001  C00005_C00006
RC01598  C02151_C03677
Enzyme
Pathway
rn00901  Indole alkaloid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Orthology
K23493  geissoschizine synthase [EC:1.3.1.36]
Other DBs
RHEA: 11379
LinkDB

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