KEGG   REACTION: R05231
Entry
R05231                      Reaction                               
Name
6-hydroxyhexanoate:NADP+ oxidoreductase
Definition
6-Hydroxyhexanoic acid + NADP+ <=> Adipate semialdehyde + NADPH + H+
Equation
Reaction class
RC00001  C00005_C00006
RC00087  C06102_C06103
Enzyme
Pathway
rn00930  Caprolactam degradation
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.2
     R05231  6-Hydroxyhexanoic acid + NADP+ <=> Adipate semialdehyde + NADPH + H+
IUBMB reaction hierarchy [BR:br08202]
 1. Oxidoreductase reactions
  1.1.1.2
   R07328  Alcohol <=> Aldehyde
    R05231  6-Hydroxyhexanoic acid <=> Adipate semialdehyde
Orthology
K00002  alcohol dehydrogenase (NADP+) [EC:1.1.1.2]
Other DBs
RHEA: 31270
LinkDB

KEGG   REACTION: R05283
Entry
R05283                      Reaction                               
Name
6-hydroxyhexanoate:NAD+ oxidoreductase
Definition
6-Hydroxyhexanoic acid + NAD+ <=> Adipate semialdehyde + NADH + H+
Equation
Reaction class
RC00001  C00003_C00004
RC00087  C06102_C06103
Enzyme
Pathway
rn00930  Caprolactam degradation
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.258
     R05283  6-Hydroxyhexanoic acid + NAD+ <=> Adipate semialdehyde + NADH + H+
Orthology
K19961  6-hydroxyhexanoate dehydrogenase [EC:1.1.1.258]
Other DBs
RHEA: 14228
LinkDB

KEGG   RCLASS: RC00087
Entry
RC00087                     RClass                                 
Definition
C1b-C4a:*-*:C1b+O1a-C1b+O4a
Reactant pair
Related class
Reaction
Enzyme
1.1.1.1         1.1.1.2         1.1.1.3         1.1.1.59        
1.1.1.61        1.1.1.66        1.1.1.73        1.1.1.77        
1.1.1.90        1.1.1.150       1.1.1.151       1.1.1.164       
1.1.1.183       1.1.1.190       1.1.1.191       1.1.1.192       
1.1.1.202       1.1.1.258       1.1.1.265       1.1.1.298       
1.1.1.309       1.1.1.313       1.1.1.433       1.1.1.-         
1.1.2.7         1.1.2.8         1.1.2.9         1.1.2.-         
1.1.3.17        1.1.3.23        1.1.5.11        1.1.99.1        
1.1.-.-         1.14.14.49      1.14.15.7
Pathway
rn00071  Fatty acid degradation
rn00073  Cutin, suberine and wax biosynthesis
rn00240  Pyrimidine metabolism
rn00260  Glycine, serine and threonine metabolism
rn00270  Cysteine and methionine metabolism
rn00300  Lysine biosynthesis
rn00350  Tyrosine metabolism
rn00360  Phenylalanine metabolism
rn00380  Tryptophan metabolism
rn00410  beta-Alanine metabolism
rn00430  Taurine and hypotaurine metabolism
rn00440  Phosphonate and phosphinate metabolism
rn00561  Glycerolipid metabolism
rn00592  alpha-Linolenic acid metabolism
rn00625  Chloroalkane and chloroalkene degradation
rn00630  Glyoxylate and dicarboxylate metabolism
rn00640  Propanoate metabolism
rn00650  Butanoate metabolism
rn00670  One carbon pool by folate
rn00720  Other carbon fixation pathways
rn00730  Thiamine metabolism
rn00930  Caprolactam degradation
rn00980  Metabolism of xenobiotics by cytochrome P450
rn00982  Drug metabolism - cytochrome P450
rn00998  Biosynthesis of various antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01200  Carbon metabolism
rn01220  Degradation of aromatic compounds
rn01230  Biosynthesis of amino acids
RModule
RM017  Ring cleavage via Baeyer-Villiger oxidation
RM019  Acyl-CoA conversion via dicarboxylate semialdehyde
Orthology
K00001  alcohol dehydrogenase [EC:1.1.1.1]
K00002  alcohol dehydrogenase (NADP+) [EC:1.1.1.2]
K00003  homoserine dehydrogenase [EC:1.1.1.3]
K00043  4-hydroxybutyrate dehydrogenase [EC:1.1.1.61]
K00048  lactaldehyde reductase [EC:1.1.1.77]
K00055  aryl-alcohol dehydrogenase [EC:1.1.1.90]
K00086  1,3-propanediol dehydrogenase [EC:1.1.1.202]
K00100  butanol dehydrogenase [EC:1.1.1.-]
K00108  choline dehydrogenase [EC:1.1.99.1]
K00114  alcohol dehydrogenase (cytochrome c) [EC:1.1.2.8]
K00121  S-(hydroxymethyl)glutathione dehydrogenase / alcohol dehydrogenase [EC:1.1.1.284 1.1.1.1]
K00499  choline monooxygenase [EC:1.14.15.7]
K08318  4-hydroxybutyrate dehydrogenase / sulfolactaldehyde 3-reductase [EC:1.1.1.61 1.1.1.373]
K09019  3-hydroxypropanoate dehydrogenase [EC:1.1.1.-]
K11440  choline dehydrogenase [EC:1.1.1.1]
K12524  bifunctional aspartokinase / homoserine dehydrogenase 1 [EC:2.7.2.4 1.1.1.3]
K12525  bifunctional aspartokinase / homoserine dehydrogenase 2 [EC:2.7.2.4 1.1.1.3]
K12901  phosphonoacetaldehyde reductase
K12904  phosphonoacetaldehyde reductase [EC:1.1.1.309]
K13774  citronellol/citronellal dehydrogenase
K13775  citronellol/citronellal dehydrogenase
K13921  1-propanol dehydrogenase
K13951  alcohol dehydrogenase 1/7 [EC:1.1.1.1]
K13952  alcohol dehydrogenase 6 [EC:1.1.1.1]
K13953  alcohol dehydrogenase, propanol-preferring [EC:1.1.1.1]
K13980  alcohol dehydrogenase 4 [EC:1.1.1.1]
K14028  methanol dehydrogenase (cytochrome c) subunit 1 [EC:1.1.2.7]
K14029  methanol dehydrogenase (cytochrome c) subunit 2 [EC:1.1.2.7]
K14465  succinate semialdehyde reductase (NADPH) [EC:1.1.1.-]
K14468  malonyl-CoA reductase / 3-hydroxypropionate dehydrogenase (NADP+) [EC:1.2.1.75 1.1.1.298]
K15039  3-hydroxypropionate dehydrogenase (NADP+) [EC:1.1.1.298]
K15373  sulfoacetaldehyde reductase [EC:1.1.1.313]
K15403  fatty acid omega-hydroxy dehydrogenase [EC:1.1.-.-]
K16066  3-hydroxy acid dehydrogenase / malonic semialdehyde reductase [EC:1.1.1.381 1.1.1.-]
K17755  choline oxidase [EC:1.1.3.17]
K18120  4-hydroxybutyrate dehydrogenase [EC:1.1.1.61]
K18121  glyoxylate/succinic semialdehyde reductase [EC:1.1.1.79 1.1.1.-]
K18602  malonic semialdehyde reductase [EC:1.1.1.-]
K18857  alcohol dehydrogenase class-P [EC:1.1.1.1]
K19961  6-hydroxyhexanoate dehydrogenase [EC:1.1.1.258]
K23146  3-hydroxyisobutyrate/3-hydroxypropionate dehydrogenase [EC:1.1.1.31 1.1.1.59]
K25985  sulfoacetaldehyde reductase (NADH) [EC:1.1.1.433]
K26209  glycolaldehyde reductase [EC:1.1.1.-]

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