KEGG   REACTION: R05282
Entry
R05282                      Reaction                               
Name
4-methylbenzyl alcohol:NAD+ oxidoreductase
Definition
4-Methylbenzyl alcohol + NAD+ <=> p-Tolualdehyde + NADH + H+
Equation
Reaction class
RC00001  C00003_C00004
RC00116  C06757_C06758
Enzyme
Pathway
rn00622  Xylene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Module
M00537  Xylene degradation, xylene => methylbenzoate
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.90
     R05282  4-Methylbenzyl alcohol + NAD+ <=> p-Tolualdehyde + NADH + H+
IUBMB reaction hierarchy [BR:br08202]
 1. Oxidoreductase reactions
  1.1.1.90
   R01487  Aromatic primary alcohol <=> Aromatic aldehyde
    R05282  4-Methylbenzyl alcohol <=> p-Tolualdehyde
Orthology
K00055  aryl-alcohol dehydrogenase [EC:1.1.1.90]
LinkDB

KEGG   RCLASS: RC00116
Entry
RC00116                     RClass                                 
Definition
C1b-C4a:*-*:C8y+O1a-C8y+O4a
Reactant pair
Related class
Reaction
Enzyme
1.1.1.1         1.1.1.65        1.1.1.90        1.1.1.91        
1.1.1.97        1.1.1.257       1.1.1.294       1.1.1.-         
1.1.3.7         1.1.3.12        1.1.3.38        1.1.3.42        
1.1.3.47        1.1.99.9        1.1.99.42       1.4.3.5         
1.14.11.6       1.14.13.122     1.17.9.1
Pathway
rn00333  Prodigiosin biosynthesis
rn00365  Furfural degradation
rn00622  Xylene degradation
rn00623  Toluene degradation
rn00626  Naphthalene degradation
rn00627  Aminobenzoate degradation
rn00750  Vitamin B6 metabolism
rn00860  Porphyrin metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
rn01240  Biosynthesis of cofactors
RModule
RM003  Methyl to carboxyl conversion on aromatic ring
Orthology
K00001  alcohol dehydrogenase [EC:1.1.1.1]
K00055  aryl-alcohol dehydrogenase [EC:1.1.1.90]
K00121  S-(hydroxymethyl)glutathione dehydrogenase / alcohol dehydrogenase [EC:1.1.1.284 1.1.1.1]
K00275  pyridoxamine 5'-phosphate oxidase [EC:1.4.3.5]
K04072  acetaldehyde dehydrogenase / alcohol dehydrogenase [EC:1.2.1.10 1.1.1.1]
K05275  pyridoxine 4-dehydrogenase [EC:1.1.1.65]
K10617  p-cumic alcohol dehydrogenase
K13600  chlorophyllide a oxygenase [EC:1.14.13.122]
K13606  chlorophyll(ide) b reductase [EC:1.1.1.294]
K13953  alcohol dehydrogenase, propanol-preferring [EC:1.1.1.1]
K13954  alcohol dehydrogenase [EC:1.1.1.1]
K18607  pyridoxine 4-oxidase [EC:1.1.3.12]
K18611  4-pyridoxate dehydrogenase [EC:1.1.99.42]
K19629  4-(hydroxymethyl)benzenesulfonate dehydrogenase [EC:1.1.1.257]
K21785  4-hydroxy-2,2'-bipyrrole-5-methanol dehydrogenase
K23998  pyridoxal 5'-phosphate synthase / NAD(P)H-hydrate epimerase [EC:1.4.3.5 5.1.99.6]

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