KEGG   REACTION: R06294
Entry
R06294                      Reaction                               
Name
ent-kaur-16-en-19-oate,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (hydroxylating)
Definition
Kaur-16-en-18-oic acid + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-7alpha-Hydroxykaur-16-en-19-oic acid + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C11874 + C03024 + C00007 <=> C11875 + C03161 + C00001
Comment
the first step of three-step reaction (see R10067, R06294+R06295+R06297)
Reaction class
RC01218  C11874_C11875
Enzyme
1.14.14.107
Pathway
rn00904  Diterpenoid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00927  Gibberellin A12 biosynthesis, GAPP => GA12
M00929  Gibberellin A1 biosynthesis, GGPP => GA1
Orthology
K04123  ent-kaurenoic acid monooxygenase [EC:1.14.14.107]
K12917  cytochrome P450 monooxygenase 1
Other DBs
RHEA: 19244
LinkDB

KEGG   RCLASS: RC01218
Entry
RC01218                     RClass                                 
Definition
C1x-C1y:*-O1a:C1x+C1z-C1x+C1z
Reactant pair
C00535_C21296    C00695_C02528    C00808_C20322
C00808_C20323    C00859_C02035    C03092_C09844
C05452_C05454    C05455_C17339    C06093_C11853
C08616_C21820    C08616_C22113    C09844_C20326
C11857_C11858    C11859_C11860    C11861_C11862
C11863_C11864    C11874_C11875    C11877_C21560
C18225_C21825    C19819_C21842    C20152_C20153
C20530_C20536    C20586_C20587
Related class
Reaction
R03009 R04826 R06294 R06333 R06334 R06335 R06336 R06341
R07204 R08784 R09868 R10045 R10047 R10076 R10372 R10373
R11349 R11656 R11975 R11980 R12008 R12367 R12550
Enzyme
1.14.11.15      1.14.13.161     1.14.13.-       1.14.14.56      
1.14.14.63      1.14.14.68      1.14.14.70      1.14.14.71      
1.14.14.107     1.14.14.133     1.14.14.139     1.14.14.171     
1.14.14.182     1.14.15.10      1.14.15.19
Pathway
rn00120  Primary bile acid biosynthesis
rn00403  Indole diterpene alkaloid biosynthesis
rn00902  Monoterpenoid biosynthesis
rn00904  Diterpenoid biosynthesis
rn00907  Pinene, camphor and geraniol degradation
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K04123  ent-kaurenoic acid monooxygenase [EC:1.14.14.107]
K04124  gibberellin 3beta-dioxygenase [EC:1.14.11.15]
K07431  sterol 12-alpha-hydroxylase [EC:1.14.14.139]
K12917  cytochrome P450 monooxygenase 1
K18393  cytochrome P450 monooxygenase [EC:1.14.13.-]
K21120  1,8-cineole 2-endo-monooxygenase [EC:1.14.14.133]
K21719  ent-sandaracopimaradiene 3-hydroxylase / syn-pimaradiene 3-monooxygenase [EC:1.14.14.70 1.14.14.68]

DBGET integrated database retrieval system