KEGG   REACTION: R06391
Entry
R06391                      Reaction                               
Name
isopropenylmethyloxepan-2-one lactonohydrolase
Definition
(3S,6R)-6-Isopropenyl-3-methyl-2-oxo-oxepanone + H2O <=> (5R)-6-Hydroxy-5-isopropenyl-2-methylhexanoate
Equation
C11403 + C00001 <=> C11406
Reaction class
RC00713  C11403_C11406
Enzyme
3.1.1.83
Pathway
rn00903  Limonene degradation
Brite
Enzymatic reactions [BR:br08201]
 3. Hydrolase reactions
  3.1  Acting on ester bonds
   3.1.1  Carboxylic-ester hydrolases
    3.1.1.83
     R06391  (3S,6R)-6-Isopropenyl-3-methyl-2-oxo-oxepanone + H2O <=> (5R)-6-Hydroxy-5-isopropenyl-2-methylhexanoate
Orthology
K14731  epsilon-lactone hydrolase [EC:3.1.1.83]
LinkDB

KEGG   RCLASS: RC00713
Entry
RC00713                     RClass                                 
Definition
C6a-C7x:O6a+*-*+O7x:C1c+O6a-C1y+O6a
O1a-O7x:*-C7x:C1b-C1x
Reactant pair
C00502_C02266    C11403_C11406    C11418_C11420
C18049_C18061
Related class
Reaction
R02427 R06391 R06393 R08970
Enzyme
3.1.1.81        3.1.1.83        3.1.1.110
Pathway
rn00040  Pentose and glucuronate interconversions
rn00903  Limonene degradation
rn01100  Metabolic pathways
RModule
RM034  Sugar degradation to aldehyde and pyruvate
Orthology
K13075  N-acyl homoserine lactone hydrolase [EC:3.1.1.81]
K14274  xylono-1,5-lactonase [EC:3.1.1.110]
K14731  epsilon-lactone hydrolase [EC:3.1.1.83]

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