KEGG   REACTION: R07059
Entry
R07059                      Reaction                               
Definition
GDP-4-dehydro-6-deoxy-D-mannose <=> GDP-4-keto-6-L-deoxygalactose
Equation
C01222 <=> C14830
Comment
epimerization by GDP-L-fucose synthase (see R05692), subsequently R07060
Ref.: 1. J Bacteriol 180:998-1001 (1998)
Reaction class
RC01531  C01222_C14830
Enzyme
1.1.1.271
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.271
     R07059  GDP-4-dehydro-6-deoxy-D-mannose <=> GDP-4-keto-6-L-deoxygalactose
LinkDB

KEGG   REACTION: R07060
Entry
R07060                      Reaction                               
Definition
GDP-4-keto-6-L-deoxygalactose + NADPH + H+ <=> GDP-L-fucose + NADP+
Equation
C14830 + C00005 + C00080 <=> C00325 + C00006
Comment
NADPH-dependent reduction by GDP-L-fucose synthase (see R05692), following after R07059
Ref.: 1. J Bacteriol 180:998-1001 (1998)
Reaction class
RC00001  C00005_C00006
RC00182  C00325_C14830
Enzyme
1.1.1.271
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.271
     R07060  GDP-4-keto-6-L-deoxygalactose + NADPH + H+ <=> GDP-L-fucose + NADP+
LinkDB

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