KEGG   REACTION: R07965
Entry
R07965                      Reaction                               
Name
7-methylxanthine:oxygen oxidoreductase (demethylating)
Definition
7-Methylxanthine + NADH + H+ + Oxygen <=> Xanthine + NAD+ + Formaldehyde + H2O
Equation
C16353 + C00004 + C00080 + C00007 <=> C00385 + C00003 + C00067 + C00001
Reaction class
RC00001  C00003_C00004
RC01797  C00067_C16353
RC01827  C00385_C16353
Enzyme
1.14.13.128
Pathway
rn00232  Caffeine metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
Module
M00915  Caffeine degradation, caffeine => xanthine
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.13  With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.13.128
     R07965  7-Methylxanthine + NADH + H+ + Oxygen <=> Xanthine + NAD+ + Formaldehyde + H2O
Orthology
K21724  7-methylxanthine demethylase [EC:1.14.13.128]
Other DBs
RHEA: 30314
LinkDB

KEGG   REACTION: R07966
Entry
R07966                      Reaction                               
Name
7-methylxanthine:oxygen oxidoreductase (demethylating)
Definition
7-Methylxanthine + NADPH + H+ + Oxygen <=> Xanthine + NADP+ + Formaldehyde + H2O
Equation
C16353 + C00005 + C00080 + C00007 <=> C00385 + C00006 + C00067 + C00001
Reaction class
RC00001  C00005_C00006
RC01797  C00067_C16353
RC01827  C00385_C16353
Enzyme
1.14.13.128
Pathway
rn00232  Caffeine metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
Module
M00915  Caffeine degradation, caffeine => xanthine
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.13  With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.13.128
     R07966  7-Methylxanthine + NADPH + H+ + Oxygen <=> Xanthine + NADP+ + Formaldehyde + H2O
Orthology
K21724  7-methylxanthine demethylase [EC:1.14.13.128]
Other DBs
RHEA: 30310
LinkDB

KEGG   RCLASS: RC01827
Entry
RC01827                     RClass                                 
Definition
N4x-N4y:*-C1a:C8x+C8y-C8x+C8y
Reactant pair
C00385_C16353    C07130_C07481    C07480_C16357
C13747_C16358
Related class
Reaction
R07943 R07959 R07960 R07963 R07964 R07965 R07966 R07971
R07972
Enzyme
1.13.12.-       1.14.13.128     1.14.14.1
Pathway
rn00232  Caffeine metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
Orthology
K07409  cytochrome P450 family 1 subfamily A2 [EC:1.14.14.1]
K21724  7-methylxanthine demethylase [EC:1.14.13.128]

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