KEGG   REACTION: R08112
Entry
R08112                      Reaction                               
Name
5-fluorocyclohexadiene-cis,cis-1,2-diol-1-carboxylate:NAD+oxidoreductase (decarboxylating)
Definition
5-Fluorocyclohexadiene-cis,cis-1,2-diol-1-carboxylate + NAD+ <=> 4-Fluorocatechol + NADH + CO2 + H+
Equation
C16479 + C00003 <=> C16473 + C00004 + C00011 + C00080
Reaction class
RC00001  C00003_C00004
RC00271  C16473_C16479
Enzyme
1.3.1.25
Pathway
rn00364  Fluorobenzoate degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.3  Acting on the CH-CH group of donors
   1.3.1  With NAD+ or NADP+ as acceptor
    1.3.1.25
     R08112  5-Fluorocyclohexadiene-cis,cis-1,2-diol-1-carboxylate + NAD+ <=> 4-Fluorocatechol + NADH + CO2 + H+
Orthology
K05783  dihydroxycyclohexadiene carboxylate dehydrogenase [EC:1.3.1.25 1.3.1.-]
LinkDB

KEGG   RCLASS: RC00271
Entry
RC00271                     RClass                                 
Definition
C1y-C8y:*-*:C1z+C2x+O1a-C8y+C8x+O1a
C1z-C8y:C6a-*:C1y+C2x+O1a-C8y+C8x+O1a
Reactant pair
C00090_C06321    C00230_C06318    C06729_C06730
C16473_C16479    C16473_C16480
Related class
Reaction
R00813 R01633 R05292 R05293 R08112 R08113
Enzyme
1.3.1.25        1.3.1.53        1.3.1.67
Pathway
rn00362  Benzoate degradation
rn00364  Fluorobenzoate degradation
rn00622  Xylene degradation
rn00624  Polycyclic aromatic hydrocarbon degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
RModule
RM005  Dihydroxylation of aromatic ring, type 1a (dioxygenase and decarboxylating dehydrogenase reactions)
Orthology
K05783  dihydroxycyclohexadiene carboxylate dehydrogenase [EC:1.3.1.25 1.3.1.-]
K18076  1,2-dihydroxy-3,5-cyclohexadiene-1,4-dicarboxylate dehydrogenase [EC:1.3.1.53]

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