REACTION: R08664
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Entry
R08664 Reaction
Name
L-leucine,NADPH:oxygen oxidoreductase (N-hydroxylating, decarboxylating)
Definition
L-Leucine + 2 Oxygen + 2 NADPH + 2 H+ <=> 3-Methylbutyraldehyde oxime + 3 H2O + 2 NADP+ + CO2
Equation
C00123
+ 2
C00007
+ 2
C00005
+ 2
C00080
<=>
C17255
+ 3
C00001
+ 2
C00006
+
C00011
Comment
multi-step reaction (similar to
R10671, R00730+R04460+R07190
)
Reaction class
RC00001
C00005_C00006
RC02295
C00123_C17255
Enzyme
1.14.13.-
Pathway
rn00966
Glucosinolate biosynthesis
rn01110
Biosynthesis of secondary metabolites
rn01210
2-Oxocarboxylic acid metabolism
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RCLASS: RC02295
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Entry
RC02295 RClass
Definition
C1c-C2b:C6a-*:C1b+N1a-C1b+N2b
N1a-N2b:*-O1b:C1c-C2b
Reactant pair
C00078_C02937
C00079_C16075
C00079_C19714
C00082_C04350
C00123_C17255
C17213_C17241
C17217_C17245
C17221_C17246
C17225_C17249
C17229_C17251
C17233_C17253
C17235_C17236
C21534_C21535
Related class
DB search
Reaction
R08160
R08652
R08655
R08664
R08665
R08670
R08672
R08673
R08674
R08675
R09578
R10671
R11646
Enzyme
1.14.13.-
1.14.14.36
1.14.14.40
1.14.14.42
1.14.14.156
Pathway
rn00380
Tryptophan metabolism
rn00966
Glucosinolate biosynthesis
rn01100
Metabolic pathways
rn01110
Biosynthesis of secondary metabolites
rn01210
2-Oxocarboxylic acid metabolism
RModule
RM030
Glucosinolate synthesis
Orthology
K11812
tryptophan N-monooxygenase [EC:
1.14.14.156
]
K11813
tryptophan N-monooxygenase [EC:
1.14.14.156
]
K12153
phenylalanine N-monooxygenase [EC:
1.14.14.40
]
K12154
homomethionine N-monooxygenase [EC:
1.14.14.42
]
K12155
homomethionine N-monooxygenase [EC:
1.14.14.42
]
K13027
tyrosine N-monooxygenase [EC:
1.14.14.36
]
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integrated database retrieval system