KEGG   REACTION: R10077
Entry
R10077                      Reaction                               
Definition
Abietinol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Abieta-7,13-dien-18,18-diol + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C11882 + C03024 + C00007 <=> C20329 + C03161 + C00001
Comment
the first step of three-step reaction (see R12122, R10077+R10078+R12123)
Reaction class
RC00001  C00005_C00006
RC03082  C11882_C20329
Enzyme
1.14.14.145
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.145
     R10077  Abietinol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Abieta-7,13-dien-18,18-diol + [Oxidized NADPH---hemoprotein reductase] + H2O
Orthology
K14040  abieta-7,13-dien-18-ol hydroxylase [EC:1.14.14.145]
Other DBs
RHEA: 31986
LinkDB

KEGG   REACTION: R10078
Entry
R10078                      Reaction                               
Definition
Abieta-7,13-dien-18,18-diol <=> Abietal + H2O
Equation
C20329 <=> C11887 + C00001
Comment
spontaneous
the second step of three-step reaction (see R12122, R10077+R10078+R12123)
Reaction class
RC03083  C11887_C20329
Enzyme
1.14.14.145
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.145
     R10078  Abieta-7,13-dien-18,18-diol <=> Abietal + H2O
Orthology
K14040  abieta-7,13-dien-18-ol hydroxylase [EC:1.14.14.145]
Other DBs
RHEA: 32198
LinkDB

KEGG   REACTION: R12123
Entry
R12123                      Reaction                               
Definition
Abietal + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Abietate + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C11887 + C03024 + C00007 <=> C06087 + C03161 + C00001
Comment
the last step of three-step reaction (see R12122, R10077+R10078+R12123)
Reaction class
RC01563  C06087_C11887
Enzyme
1.14.14.145
Pathway
rn00904  Diterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.145
     R12123  Abietal + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Abietate + [Oxidized NADPH---hemoprotein reductase] + H2O
Orthology
K14040  abieta-7,13-dien-18-ol hydroxylase [EC:1.14.14.145]
LinkDB

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