KEGG   REACTION: R10459
Entry
R10459                      Reaction                               
Name
dTDP-5-dimethyl-L-lyxose:NAD+ 4-oxidoreductase
Definition
dTDP-4-oxo-5-C-methyl-L-rhamnose + NADH + H+ <=> dTDP-5-dimethyl-L-lyxose + NAD+
Equation
C11460 + C00004 + C00080 <=> C12481 + C00003
Comment
4-ketoreductase, NovS CloS CouS
Reaction class
RC00001  C00003_C00004
RC00261  C11460_C12481
Enzyme
1.1.1.-
Pathway
rn00523  Polyketide sugar unit biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01250  Biosynthesis of nucleotide sugars
Module
M00795  dTDP-beta-L-noviose biosynthesis
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.-
     R10459  dTDP-4-oxo-5-C-methyl-L-rhamnose + NADH + H+ <=> dTDP-5-dimethyl-L-lyxose + NAD+
Orthology
K17625  dTDP-4-keto-6-deoxyhexose reductase [EC:1.1.1.-]
LinkDB

KEGG   RCLASS: RC00261
Entry
RC00261                     RClass                                 
Definition
C1y-C5x:*-*:C1y+C1z+O1a-C1y+C1z+O5x
Reactant pair
C05141_C05300    C11460_C12481    C11915_C11916
C12320_C12321    C12320_C12322
Related class
Reaction
R04681 R04682 R06436 R06629 R06630 R10459
Enzyme
1.1.1.62        1.1.1.-
Pathway
rn00140  Steroid hormone biosynthesis
rn00523  Polyketide sugar unit biosynthesis
rn01055  Biosynthesis of vancomycin group antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01250  Biosynthesis of nucleotide sugars
RModule
RM036  Epimerization and reduction in deoxysugar biosynthesis
Orthology
K00044  17beta-estradiol 17-dehydrogenase [EC:1.1.1.62]
K10251  17beta-estradiol 17-dehydrogenase / very-long-chain 3-oxoacyl-CoA reductase [EC:1.1.1.62 1.1.1.330]
K13318  dTDP-4-keto-6-deoxy-L-hexose 4-reductase [EC:1.1.1.-]
K13368  17beta-estradiol 17-dehydrogenase / 3alpha(17beta)-hydroxysteroid dehydrogenase (NAD+) [EC:1.1.1.62 1.1.1.239]
K13369  17beta-estradiol 17-dehydrogenase / all-trans-retinol dehydrogenase (NAD+) / 3alpha(17beta)-hydroxysteroid dehydrogenase (NAD+) [EC:1.1.1.62 1.1.1.105 1.1.1.239]
K13370  17beta-estradiol 17-dehydrogenase / 3alpha(17beta)-hydroxysteroid dehydrogenase (NAD+) / 3-oxoacyl-[acyl-carrier protein] reductase alpha subunit [EC:1.1.1.62 1.1.1.239]
K13373  17beta-estradiol 17-dehydrogenase / 3beta-hydroxysteroid 3-dehydrogenase [EC:1.1.1.62 1.1.1.270]
K16439  reductase EvaE
K17625  dTDP-4-keto-6-deoxyhexose reductase [EC:1.1.1.-]
K18836  reductase VcaE

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