KEGG   REACTION: R10937
Entry
R10937                      Reaction                               
Name
alpha-D-sedoheptulopyranose-7-phosphate phosphate-lyase (cyclizing, 2-epi-5-epi-valiolone-forming)
Definition
alpha-D-Sedoheptulopyranose 7-phosphate <=> 2-epi-5-epi-Valiolone + Orthophosphate
Equation
C20956 <=> C17691 + C00009
Reaction class
RC03308  C17691_C20956
Enzyme
4.2.3.152
Pathway
rn00525  Acarbose and validamycin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00814  Acarbose biosynthesis, sedoheptulopyranose-7P => acarbose
M00815  Validamycin A biosynthesis, sedoheptulopyranose-7P => validamycin A
Orthology
K19969  2-epi-5-epi-valiolone synthase [EC:4.2.3.152]
Other DBs
RHEA: 44187
LinkDB

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