KEGG   REACTION: R11250
Entry
R11250                      Reaction                               
Definition
NDP-1-epi-valienol + 2-Amino-1,5-anhydro-2-deoxyglucitol <=> Salbostatin 6'-phosphate + NDP
Equation
Reaction class
RC03401  C21210_C21211
Enzyme
Pathway
rn00525  Acarbose and validamycin biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.5  Transferring alkyl or aryl groups, other than methyl groups
   2.5.1  Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
    2.5.1.135
     R11250  NDP-1-epi-valienol + 2-Amino-1,5-anhydro-2-deoxyglucitol <=> Salbostatin 6'-phosphate + NDP
Orthology
K20436  validamine 7-phosphate valienyltransferase [EC:2.5.1.135]
Reference
1  [PMID:18648803]
  Authors
Choi WS, Wu X, Choeng YH, Mahmud T, Jeong BC, Lee SH, Chang YK, Kim CJ, Hong SK
  Title
Genetic organization of the putative salbostatin biosynthetic gene cluster including the 2-epi-5-epi-valiolone synthase gene in Streptomyces albus ATCC 21838.
  Journal
Appl Microbiol Biotechnol 80:637-45 (2008)
DOI:10.1007/s00253-008-1591-2
LinkDB

KEGG   RCLASS: RC03401
Entry
RC03401                     RClass                                 
Definition
C1y-C1y:N1b+*-*+O2b:C1y+C2x-C1y+C2x
Reactant pair
Related class
Reaction
Enzyme
2.4.-.-         2.5.1.135
Pathway
rn00525  Acarbose and validamycin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K20430  glycosyltransferase AcbS [EC:2.4.-.-]
K20436  validamine 7-phosphate valienyltransferase [EC:2.5.1.135]

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