KEGG   REACTION: R11382
Entry
R11382                      Reaction                               
Name
aurachin C:NADH:oxygen oxidoreductase (4-hydroxy-2-methyl-3-oxo-4-farnesyl-3,4-dihydroquinoline-1-oxide-forming)
Definition
Aurachin C + NADH + H+ + Oxygen <=> 4-Hydroxy-2-methyl-3-oxo-4-[(2E,6E)-farnesyl]-3,4-dihydroquinoline 1-oxide + NAD+ + H2O
Equation
C21330 + C00004 + C00080 + C00007 <=> C21141 + C00003 + C00001
Comment
two-step reaction (see R11384+R11386)
Reaction class
RC03422  C21141_C21330
Enzyme
1.14.13.222
Pathway
rn00998  Biosynthesis of various antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00848  Aurachin biosynthesis, anthranilate => aurachin A
Orthology
K21272  aurachin C monooxygenase/isomerase [EC:1.14.13.222]
Other DBs
RHEA: 49003
LinkDB

KEGG   REACTION: R11383
Entry
R11383                      Reaction                               
Name
aurachin C:NADPH:oxygen oxidoreductase (4-hydroxy-2-methyl-3-oxo-4-farnesyl-3,4-dihydroquinoline-1-oxide-forming)
Definition
Aurachin C + NADPH + H+ + Oxygen <=> 4-Hydroxy-2-methyl-3-oxo-4-[(2E,6E)-farnesyl]-3,4-dihydroquinoline 1-oxide + NADP+ + H2O
Equation
C21330 + C00005 + C00080 + C00007 <=> C21141 + C00006 + C00001
Comment
two-step reaction (see R11385+R11386)
Reaction class
RC03422  C21141_C21330
Enzyme
1.14.13.222
Pathway
rn00998  Biosynthesis of various antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00848  Aurachin biosynthesis, anthranilate => aurachin A
Orthology
K21272  aurachin C monooxygenase/isomerase [EC:1.14.13.222]
Other DBs
RHEA: 49007
LinkDB

KEGG   RCLASS: RC03422
Entry
RC03422                     RClass                                 
Definition
C1b-C1b:C1z+*-*+C8y:C2b-C2b
C1z-C8y:C1b-*:C5x+C8y+O1a-C8y+C8y+O5x
C5x-C8y:O5x+*-*+C1b:C1z+C2y-C8y+C8y
N2y-N4y:*-*:C2y+C8y+O3a-C8y+C8y+O1b
Reactant pair
C21141_C21330
Related class
Reaction
R11382 R11383
Enzyme
1.14.13.222
Pathway
rn00998  Biosynthesis of various antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K21272  aurachin C monooxygenase/isomerase [EC:1.14.13.222]

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