KEGG   REACTION: R11598
Entry
R11598                      Reaction                               
Name
(E)-2-methylpropanal oxime,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
(E)-2-Methylpropanal oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Acetone cyanohydrin + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C03219 + C03024 + C00007 <=> C02659 + C03161 + 2 C00001
Comment
three-step reaction (see R10034+R11641+R11642)
Reaction class
RC03032  C02659_C03219
Enzyme
1.14.14.41
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.41
     R11598  (E)-2-Methylpropanal oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Acetone cyanohydrin + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Other DBs
RHEA: 51955
LinkDB

KEGG   REACTION: R10034
Entry
R10034                      Reaction                               
Definition
(E)-2-Methylpropanal oxime <=> (Z)-2-Methylpropanal oxime
Equation
C03219 <=> C20315
Comment
spontaneous
the first step of three-step reaction (see R11598, R10034+R11641+R11642)
Reaction class
RC03010  C03219_C20315
Enzyme
1.14.14.41
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.41
     R10034  (E)-2-Methylpropanal oxime <=> (Z)-2-Methylpropanal oxime
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51959
LinkDB

KEGG   REACTION: R11641
Entry
R11641                      Reaction                               
Definition
(Z)-2-Methylpropanal oxime <=> Isobutyronitrile + H2O
Equation
C20315 <=> C02420 + C00001
Comment
the second step of three-step reaction (see R11598, R10034+R11641+R11642)
Reaction class
RC03480  C02420_C20315
Enzyme
1.14.14.41
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.41
     R11641  (Z)-2-Methylpropanal oxime <=> Isobutyronitrile + H2O
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51963
LinkDB

KEGG   REACTION: R11642
Entry
R11642                      Reaction                               
Definition
Isobutyronitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Acetone cyanohydrin + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C02420 + C03024 + C00007 <=> C02659 + C03161 + C00001
Comment
the last step of three-step reaction (see R11598, R10034+R11641+R11642)
Reaction class
RC03495  C02420_C02659
Enzyme
1.14.14.41
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.41
     R11642  Isobutyronitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Acetone cyanohydrin + [Oxidized NADPH---hemoprotein reductase] + H2O
Orthology
K16265  (E)-2-methylbutanal oxime monooxygenase [EC:1.14.14.41]
Other DBs
RHEA: 51967
LinkDB

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