KEGG   REACTION: R11663
Entry
R11663                      Reaction                               
Name
4-keto-2-undecylpyrroline,NADPH: oxidoreductase
Definition
4-Keto-2-undecylpyrroline + NADPH + H+ <=> 2-Undecylpyrrole + NADP+ + H2O
Equation
Comment
NADH (see R11666)
Reaction class
RC03484  C21573_C21574
Pathway
rn00333  Prodigiosin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00838  Undecylprodigiosin biosynthesis, L-proline => undecylprodigiosin
Orthology
K21793  oxidoreductase
Reference
1  [PMID:15853884]
  Authors
Williamson NR, Simonsen HT, Ahmed RA, Goldet G, Slater H, Woodley L, Leeper FJ, Salmond GP
  Title
Biosynthesis of the red antibiotic, prodigiosin, in Serratia: identification of a novel 2-methyl-3-n-amyl-pyrrole (MAP) assembly pathway, definition of the terminal condensing enzyme, and implications for undecylprodigiosin biosynthesis in Streptomyces.
  Journal
Mol Microbiol 56:971-89 (2005)
DOI:10.1111/j.1365-2958.2005.04602.x
LinkDB

KEGG   REACTION: R11666
Entry
R11666                      Reaction                               
Name
4-keto-2-undecylpyrroline,NADH: oxidoreductase
Definition
4-Keto-2-undecylpyrroline + NADH + H+ <=> 2-Undecylpyrrole + NAD+ + H2O
Equation
Comment
NADPH+ (see R11663)
Reaction class
RC03484  C21573_C21574
Pathway
rn00333  Prodigiosin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00838  Undecylprodigiosin biosynthesis, L-proline => undecylprodigiosin
Orthology
K21793  oxidoreductase
Reference
1  [PMID:15853884]
  Authors
Williamson NR, Simonsen HT, Ahmed RA, Goldet G, Slater H, Woodley L, Leeper FJ, Salmond GP
  Title
Biosynthesis of the red antibiotic, prodigiosin, in Serratia: identification of a novel 2-methyl-3-n-amyl-pyrrole (MAP) assembly pathway, definition of the terminal condensing enzyme, and implications for undecylprodigiosin biosynthesis in Streptomyces.
  Journal
Mol Microbiol 56:971-89 (2005)
DOI:10.1111/j.1365-2958.2005.04602.x
LinkDB

KEGG   RCLASS: RC03484
Entry
RC03484                     RClass                                 
Definition
C1x-C8x:*-*:C5x+N1x-C8x+N4x
C5x-C8x:O5x-*:C1x+C2x-C8x+C8x
Reactant pair
Related class
Reaction
Pathway
rn00333  Prodigiosin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K21793  oxidoreductase

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