KEGG   REACTION: R11688
Entry
R11688                      Reaction                               
Name
(S)-1-hydroxy-N-methylcanadine,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (13-hydroxylating)
Definition
(S)-1-Hydroxy-N-methylcanadine + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (13S,14R)-1,13-Dihydroxy-N-methylcanadine + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C21586 + C03024 + C00007 <=> C21587 + C03161 + C00001
Comment
1-hydroxy-N-methylcanadine 13-hydroxylase
Reaction class
RC01552  C21586_C21587
Enzyme
1.14.14.163
Pathway
rn00950  Isoquinoline alkaloid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00946  Noscapine biosynthesis, (S)-reticuline => noscapine
Orthology
K22094  (S)-1-hydroxy-N-methylcanadine 13-hydroxylase [EC:1.14.14.163]
LinkDB

KEGG   RCLASS: RC01552
Entry
RC01552                     RClass                                 
Definition
C1x-C1y:*-O1a:C1y+C8y-C1y+C8y
Reactant pair
C03648_C09320    C05906_C06562    C05909_C12127
C07493_C07495    C10552_C21185    C10556_C10874
C21586_C21587
Related class
Reaction
R06532 R06533 R06615 R08322 R11212 R11688 R12127
Enzyme
1.14.14.132     1.14.14.163     1.17.1.3
Pathway
rn00941  Flavonoid biosynthesis
rn00950  Isoquinoline alkaloid biosynthesis
rn00982  Drug metabolism - cytochrome P450
rn00999  Biosynthesis of various plant secondary metabolites
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K13081  leucoanthocyanidin reductase [EC:1.17.1.3]
K22094  (S)-1-hydroxy-N-methylcanadine 13-hydroxylase [EC:1.14.14.163]

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