KEGG   REACTION: R12178
Entry
R12178                      Reaction                               
Name
cyclooctat-9-ene-5,7-diol,hydrogen-donor:oxygen oxidoreductase (18-hydroxylating)
Definition
Cyclooctat-9-ene-5,7-diol + Reduced acceptor + Oxygen <=> Cyclooctatin + Acceptor + H2O
Equation
C21978 + C00030 + C00007 <=> C21979 + C00028 + C00001
Reaction class
RC03228  C21978_C21979
Enzyme
1.14.99.62
Pathway
rn00997  Biosynthesis of various other secondary metabolites
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00921  Cyclooctatin biosynthesis, dimethylallyl-PP + isopentenyl-PP => cyclooctatin
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.99  Miscellaneous
    1.14.99.62
     R12178  Cyclooctat-9-ene-5,7-diol + Reduced acceptor + Oxygen <=> Cyclooctatin + Acceptor + H2O
Orthology
K22998  cyclooctatin synthase [EC:1.14.99.62]
Other DBs
RHEA: 56827
LinkDB

KEGG   RCLASS: RC03228
Entry
RC03228                     RClass                                 
Definition
C1a-C1b:*-O1a:C1y-C1y
Reactant pair
C11522_C22117    C12002_C20760    C15683_C15684
C21978_C21979
Related class
Reaction
R10656 R10875 R12178 R12372
Enzyme
1.14.13.-       1.14.15.34      1.14.18.11      1.14.99.62
Pathway
rn00522  Biosynthesis of 12-, 14- and 16-membered macrolides
rn00997  Biosynthesis of various other secondary metabolites
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Orthology
K15991  20-oxo-5-O-mycaminosyltylactone 23-monooxygenase [EC:1.14.15.34]
K22998  cyclooctatin synthase [EC:1.14.99.62]
K24292  mycinamicin VIII C21 methyl hydroxylase [EC:1.14.-.-]
K24530  ferredoxin

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