KEGG   REACTION: R13331
Entry
R13331                      Reaction                               
Definition
17-Dehydropreakuammicine hydrate <=> Akuammicine + Formate
Equation
C22961 <=> C09025 + C00058
Comment
spontaneous
the last step of four-step reaction (see R13381, R13342+R13329+R13382+R13331)
Enzyme
1.14.19.80
Pathway
rn00901  Indole alkaloid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.19  With oxidation of a pair of donors resulting in the reduction of O2 to two molecules of water
    1.14.19.80
     R13331  17-Dehydropreakuammicine hydrate <=> Akuammicine + Formate
Orthology
K27780  (19E)-geissoschizine oxidase [EC:1.14.19.80]
Reference
1  [PMID:35794473]
  Authors
Hong B, Grzech D, Caputi L, Sonawane P, Lopez CER, Kamileen MO, Hernandez Lozada NJ, Grabe V, O'Connor SE
  Title
Biosynthesis of strychnine.
  Journal
Nature 607:617-622 (2022)
DOI:10.1038/s41586-022-04950-4
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