KEGG   REACTION: R13441
Entry
R13441                      Reaction                               
Name
5-methoxy-2-methyl-3-(all-trans-polyprenyl)benzene-1,4-diol,acceptor:2-(all-trans-polyprenyl)phenol oxidoreductase (3-hydroxylating)
Definition
5-Methoxy-2-methyl-3-(all-trans-polyprenyl)benzene-1,4-diol + Prephenate + Acceptor <=> 3-Demethylubiquinol + Phenylpyruvate + CO2 + Reduced acceptor
Equation
C19859 + C00254 + C00028 <=> C21860 + C00166 + C00011 + C00030
Comment
general reaction
Reaction class
RC00236  C19859_C21860
Enzyme
1.97.1.15
Pathway
rn00130  Ubiquinone and other terpenoid-quinone biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01240  Biosynthesis of cofactors
Module
M00989  Ubiquinone biosynthesis, O2-independent, prokaryotes, chorismate (+ polyprenyl-PP) => ubiquinol
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.97  Other oxidoreductases
   1.97.1  Sole sub-subclass for oxidoreductases that do not belong in the other subclasses
    1.97.1.15
     R13441  5-Methoxy-2-methyl-3-(all-trans-polyprenyl)benzene-1,4-diol + Prephenate + Acceptor <=> 3-Demethylubiquinol + Phenylpyruvate + CO2 + Reduced acceptor
Orthology
K24844  2-(all-trans-polyprenyl)phenol 6-hydroxylase (prephenate) UbiU [EC:1.97.1.15]
K24845  2-(all-trans-polyprenyl)phenol 6-hydroxylase (prephenate) UbiV [EC:1.97.1.15]
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