KEGG   REACTION: R13532
Entry
R13532                      Reaction                               
Name
pyridin-1-ium-3,5-bisthiocarboxylate mononucleotide sufo-lyase
Definition
[Protein]-L-cysteine + Pyridinium-3-carboxy-5-thiocarboxylic acid mononucleotide + ATP + Reduced acceptor <=> [Protein]-L-cysteine + Pyridinium-3,5-bisthiocarboxylate mononucleotide + AMP + Diphosphate + Acceptor
Equation
C02743 + C21878 + C00002 + C00030 <=> C02743 + C21767 + C00020 + C00013 + C00028
Comment
two-step reaction (see R12063+R13533)
Enzyme
4.4.1.45
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.4  Carbon-sulfur lyases
   4.4.1  Carbon-sulfur lyases (only sub-subclass identified to date)
    4.4.1.45
     R13532  [Protein]-L-cysteine + Pyridinium-3-carboxy-5-thiocarboxylic acid mononucleotide + ATP + Reduced acceptor <=> [Protein]-L-cysteine + Pyridinium-3,5-bisthiocarboxylate mononucleotide + AMP + Diphosphate + Acceptor
LinkDB

KEGG   REACTION: R12063
Entry
R12063                      Reaction                               
Definition
ATP + Pyridinium-3-carboxy-5-thiocarboxylic acid mononucleotide <=> Diphosphate + 1-(5-O-Phospho-beta-D-ribofuranosyl)-5-(sulfanylcarbonyl)pyridin-1-ium-3-carbonyl adenylate
Equation
C00002 + C21878 <=> C00013 + C21879
Comment
the first step of three-step reaction (see R12066, R12053+R12064+R12065)
the first step of two-step reaction (see R13532, R12063+R13533)
Reaction class
RC00043  C21878_C21879
Enzyme
4.4.1.37        4.4.1.45
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.4  Carbon-sulfur lyases
   4.4.1  Carbon-sulfur lyases (only sub-subclass identified to date)
    4.4.1.37
     R12063  ATP + Pyridinium-3-carboxy-5-thiocarboxylic acid mononucleotide <=> Diphosphate + 1-(5-O-Phospho-beta-D-ribofuranosyl)-5-(sulfanylcarbonyl)pyridin-1-ium-3-carbonyl adenylate
    4.4.1.45
     R12063  ATP + Pyridinium-3-carboxy-5-thiocarboxylic acid mononucleotide <=> Diphosphate + 1-(5-O-Phospho-beta-D-ribofuranosyl)-5-(sulfanylcarbonyl)pyridin-1-ium-3-carbonyl adenylate
Orthology
K06864  cysteine-dependent pyridinium-3,5-bisthiocarboxylic acid mononucleotide synthase [EC:4.4.1.37 4.4.1.45]
LinkDB

KEGG   REACTION: R13533
Entry
R13533                      Reaction                               
Definition
[Protein]-L-cysteine + 1-(5-O-Phospho-beta-D-ribofuranosyl)-5-(sulfanylcarbonyl)pyridin-1-ium-3-carbonyl adenylate + Reduced acceptor <=> [Protein]-L-cysteine + Pyridinium-3,5-bisthiocarboxylate mononucleotide + AMP + Acceptor
Equation
C02743 + C21879 + C00030 <=> C02743 + C21767 + C00020 + C00028
Comment
the second step of two-step reaction (see R13532, R12063+R13533)
Enzyme
4.4.1.45
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.4  Carbon-sulfur lyases
   4.4.1  Carbon-sulfur lyases (only sub-subclass identified to date)
    4.4.1.45
     R13533  [Protein]-L-cysteine + 1-(5-O-Phospho-beta-D-ribofuranosyl)-5-(sulfanylcarbonyl)pyridin-1-ium-3-carbonyl adenylate + Reduced acceptor <=> [Protein]-L-cysteine + Pyridinium-3,5-bisthiocarboxylate mononucleotide + AMP + Acceptor
LinkDB

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