KEGG   ENZYME: 2.5.1.123Help
Entry
EC 2.5.1.123                Enzyme                                 

Name
flaviolin linalyltransferase;
Fnq26
Class
Transferases;
Transferring alkyl or aryl groups, other than methyl groups;
Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
BRITE hierarchy
Sysname
geranyl-diphosphate:flaviolin 3-linalyltransferase
Reaction(IUBMB)
geranyl diphosphate + flaviolin = 3-linalylflaviolin + diphosphate [RN:R10969]
Reaction(KEGG)
Substrate
geranyl diphosphate [CPD:C00341];
flaviolin [CPD:C18012]
Product
3-linalylflaviolin [CPD:C20984];
diphosphate [CPD:C00013]
Comment
Does not require Mg2+ or any other metal ions. Isolated from the bacterium Streptomyces cinnamonensis. In vitro the enzyme also forms traces of 3-geranylflaviolin.
History
EC 2.5.1.123 created 2014
Orthology
K21340  flaviolin linalyltransferase
Reference
1  [PMID:17543953]
  Authors
Haagen Y, Unsold I, Westrich L, Gust B, Richard SB, Noel JP, Heide L
  Title
A soluble, magnesium-independent prenyltransferase catalyzes reverse and regular  C-prenylations and O-prenylations of aromatic substrates.
  Journal
FEBS Lett 581:2889-93 (2007)
DOI:10.1016/j.febslet.2007.05.031
  Sequence
Other DBs
ExplorEnz - The Enzyme Database: 2.5.1.123
IUBMB Enzyme Nomenclature: 2.5.1.123
ExPASy - ENZYME nomenclature database: 2.5.1.123
BRENDA, the Enzyme Database: 2.5.1.123
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