Entry |
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Name |
2-amino-4,5-dihydroxy-6-oxo-7-(phosphooxy)heptanoate synthase;
griI (gene name)
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Class |
Lyases;
Carbon-carbon lyases;
Aldehyde-lyases
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Sysname |
2-amino-4,5-dihydroxy-6-oxo-7-(phosphooxy)heptanoate L-aspartate 4-semialdehyde-lyase (glycerone phosphate-forming)
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Reaction(IUBMB) |
2-amino-4,5-dihydroxy-6-oxo-7-(phosphooxy)heptanoate = glycerone phosphate + L-aspartate 4-semialdehyde [RN: R10673]
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Reaction(KEGG) |
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Substrate |
2-amino-4,5-dihydroxy-6-oxo-7-(phosphooxy)heptanoate [CPD: C20644]
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Product |
glycerone phosphate [CPD: C00111];
L-aspartate 4-semialdehyde [CPD: C00441]
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Comment |
Part of the pathway for the biosynthesis of grixazone, a mixture of yellow pigments produced by the bacterium Streptomyces griseus.
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History |
EC 4.1.2.56 created 2014
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Pathway |
ec00997 | Biosynthesis of various secondary metabolites - part 3 |
ec01110 | Biosynthesis of secondary metabolites |
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Orthology |
K18287 | 2-amino-4,5-dihydroxy-6-oxo-7-(phosphooxy)heptanoate synthase |
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Genes |
» show all
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Reference |
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Authors |
Suzuki H, Ohnishi Y, Furusho Y, Sakuda S, Horinouchi S |
Title |
Novel benzene ring biosynthesis from C(3) and C(4) primary metabolites by two enzymes. |
Journal |
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Sequence |
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Other DBs |
ExplorEnz - The Enzyme Database: | 4.1.2.56 |
ExPASy - ENZYME nomenclature database: | 4.1.2.56 |
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LinkDB |
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