KEGG   ENZYME: 2.3.1.145
Entry
EC 2.3.1.145                Enzyme                                 
Name
piperidine N-piperoyltransferase;
piperidine piperoyltransferase;
piperoyl-CoA:piperidine N-piperoyltransferase
Class
Transferases;
Acyltransferases;
Transferring groups other than aminoacyl groups
Sysname
(E,E)-piperoyl-CoA:piperidine N-piperoyltransferase
Reaction(IUBMB)
(E,E)-piperoyl-CoA + piperidine = CoA + N-[(E,E)-piperoyl]-piperidine [RN:R03994]
Reaction(KEGG)
R03994
Substrate
(E,E)-piperoyl-CoA [CPD:C02611];
piperidine [CPD:C01746]
Product
CoA [CPD:C00010];
N-[(E,E)-piperoyl]-piperidine [CPD:C03882]
Comment
Pyrrolidine and 3-pyrroline can also act as acceptors, but more slowly.
History
EC 2.3.1.145 created 1992
Pathway
ec00960  Tropane, piperidine and pyridine alkaloid biosynthesis
Reference
1
  Authors
Geisler JG, Gross GG.
  Title
The biosynthesis of piperine in Piper nigrum.
  Journal
Phytochemistry 29:489-492 (1990)
Other DBs
ExplorEnz - The Enzyme Database: 2.3.1.145
IUBMB Enzyme Nomenclature: 2.3.1.145
ExPASy - ENZYME nomenclature database: 2.3.1.145
BRENDA, the Enzyme Database: 2.3.1.145
CAS: 126806-22-2
LinkDB

KEGG   REACTION: R03994
Entry
R03994                      Reaction                               
Name
(E,E)-piperoyl-CoA:piperidine N-piperoyltransferase
Definition
(E,E)-Piperoyl-CoA + Piperidine <=> CoA + Piperine
Equation
Reaction class
RC00004  C00010_C02611
RC01045  C01746_C03882
Enzyme
Pathway
rn00960  Tropane, piperidine and pyridine alkaloid biosynthesis
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.1  Transferring groups other than aminoacyl groups
    2.3.1.145
     R03994  (E,E)-Piperoyl-CoA + Piperidine <=> CoA + Piperine
Other DBs
RHEA: 14564
LinkDB

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