aliphatic aldoxime dehydratase;
aliphatic aldoxime hydro-lyase
aliphatic aldoxime hydro-lyase (aliphatic-nitrile-forming)
an aliphatic aldoxime = an aliphatic nitrile + H2O [RN:
aliphatic aldoxime [CPD:
The enzyme from Pseudomonas chlororaphis contains Ca2+ and protoheme IX, the iron of which must be in the form Fe(II) for activity. The enzyme exhibits a strong preference for aliphatic aldoximes, such as butyraldoxime and acetaldoxime, over aromatic aldoximes, such as pyridine-2-aldoxime, which is a poor substrate. No activity was found with the aromatic aldoximes benzaldoxime and pyridine-4-aldoxime.
EC 188.8.131.52 created 2004 as EC 184.108.40.206, transferred 2021 to EC 220.127.116.11
K13028 aliphatic aldoxime dehydratase
VAP: Vapar_0670 Vapar_2540
HRB: Hrubri_2880(oxdA) Hrubri_3579(oxdA)
PSIN: CAK95_03820 CAK95_28650
SNEA: NBZ79_14860 NBZ79_17720
RKO: JWS14_00645 JWS14_16535 » show all
Oinuma K, Hashimoto Y, Konishi K, Goda M, Noguchi T, Higashibata H, Kobayashi M
Novel aldoxime dehydratase involved in carbon-nitrogen triple bond synthesis of Pseudomonas chlororaphis B23. Sequencing, gene expression, purification, and characterization.
Xie SX, Kato Y, Komeda H, Yoshida S, Asano Y
A gene cluster responsible for alkylaldoxime metabolism coexisting with nitrile hydratase and amidase in Rhodococcus globerulus A-4.
Kato Y, Yoshida S, Xie SX, Asano Y.
Aldoxime dehydratase co-existing with nitrile hydratase and amidase in the iron-type nitrile hydratase-producer Rhodococcus sp. N-771.
ExplorEnz - The Enzyme Database: 18.104.22.168
ExPASy - ENZYME nomenclature database: 22.214.171.124
BRENDA, the Enzyme Database: 126.96.36.199
LinkDB All DBs