KEGG   ORTHOLOGY: K25584
Entry
K25584                      KO                                     
Symbol
CYP80F1
Name
littorine mutase [EC:1.14.14.195]
Pathway
map00960  Tropane, piperidine and pyridine alkaloid biosynthesis
map01100  Metabolic pathways
map01110  Biosynthesis of secondary metabolites
Reaction
R12954  littorine,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (hyoscyamine aldehyde forming)
Brite
KEGG Orthology (KO) [BR:ko00001]
 09100 Metabolism
  09110 Biosynthesis of other secondary metabolites
   00960 Tropane, piperidine and pyridine alkaloid biosynthesis
    K25584  CYP80F1; littorine mutase
 09180 Brite Hierarchies
  09181 Protein families: metabolism
   00199 Cytochrome P450
    K25584  CYP80F1; littorine mutase
Enzymes [BR:ko01000]
 1. Oxidoreductases
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.195  littorine mutase
     K25584  CYP80F1; littorine mutase
Cytochrome P450 [BR:ko00199]
 Cytochrome P450, plant type
  CYP80 family
   K25584  CYP80F1; littorine mutase
Genes
AG: ABD39696(CYP80F1)
Reference
PMID:16720272
  Authors
Li R, Reed DW, Liu E, Nowak J, Pelcher LE, Page JE, Covello PS.
  Title
Functional genomic analysis of alkaloid biosynthesis in Hyoscyamus niger reveals a cytochrome P450 involved in littorine rearrangement.
  Journal
Chem Biol 13:513-20 (2006)
DOI:10.1016/j.chembiol.2006.03.005
  Sequence
[ag:ABD39696]
LinkDB

KEGG   REACTION: R12954
Entry
R12954                      Reaction                               
Name
littorine,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (hyoscyamine aldehyde forming)
Definition
Littorine + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Hyoscyamine aldehyde + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C10860 + C03024 + C00007 <=> C22466 + C03161 + 2 C00001
Comment
littorine mutase
two-step reaction (see R13503+R13504)
Enzyme
1.14.14.195
Pathway
rn00960  Tropane, piperidine and pyridine alkaloid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.195
     R12954  Littorine + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Hyoscyamine aldehyde + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Orthology
K25584  littorine mutase [EC:1.14.14.195]
LinkDB

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