KEGG   REACTION: R05295
Entry
R05295                      Reaction                               
Name
4-methylcatechol:oxygen 2,3-oxidoreductase(decyclizing)
Definition
4-Methylcatechol + Oxygen <=> 2-Hydroxy-5-methyl-cis,cis-muconic semialdehyde
Equation
C06730 + C00007 <=> C06760
Reaction class
RC00643  C06730_C06760
Enzyme
1.13.11.2
Pathway
rn00622  Xylene degradation
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Module
M00569  Catechol meta-cleavage, catechol => acetyl-CoA / 4-methylcatechol => propanoyl-CoA
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.13  Acting on single donors with incorporation of molecular oxygen (oxygenases)
   1.13.11  With incorporation of two atoms of oxygen
    1.13.11.2
     R05295  4-Methylcatechol + Oxygen <=> 2-Hydroxy-5-methyl-cis,cis-muconic semialdehyde
Orthology
K00446  catechol 2,3-dioxygenase [EC:1.13.11.2]
K07104  catechol 2,3-dioxygenase [EC:1.13.11.2]
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