KEGG   REACTION: R05824
Entry
R05824                      Reaction                               
Definition
4,21-Dehydrocorynantheine aldehyde <=> 4,21-Dehydrogeissoschizine
Equation
Comment
spontaneous(following EC3.2.1.105 or R03820+R05844+R05845 reaction)
Reaction class
RC01605  C03677_C11679
Pathway
rn00901  Indole alkaloid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00981  Geissoschizine biosynthesis, tryptophan => geissoschizine
Reference
1
  Authors
Stoeckigt J, Hemscheidt T, Hofle G, Heinstein P, Formacek V.
  Title
Steric course of hydrogen transfer during enzymatic formation of 3alpha-heteroyohimbine alkaloids
  Journal
Biochemistry 22:3448-3452 (1983)
DOI:10.1021/bi00283a022
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