KEGG   REACTION: R08168
Entry
R08168                      Reaction                               
Name
indole-3-acetaldehyde-oxime,NADPH:oxidoreductase
Definition
Indole-3-acetaldehyde oxime + L-Cysteine + NADPH + Oxygen + H+ <=> S-(Indolylmethylthiohydroximoyl)-L-cysteine + NADP+ + 2 H2O
Equation
C02937 + C00097 + C00005 + C00007 + C00080 <=> C16518 + C00006 + 2 C00001
Comment
two-step reaction (see R08607+R08608)
Reaction class
RC00001  C00005_C00006
RC01705  C00097_C16518
RC02210  C02937_C16518
Enzyme
1.14.14.45
Pathway
rn00380  Tryptophan metabolism
rn00966  Glucosinolate biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Module
M00370  Glucosinolate biosynthesis, tryptophan => glucobrassicin
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.45
     R08168  Indole-3-acetaldehyde oxime + L-Cysteine + NADPH + Oxygen + H+ <=> S-(Indolylmethylthiohydroximoyl)-L-cysteine + NADP+ + 2 H2O
Orthology
K11818  aromatic aldoxime N-monooxygenase [EC:1.14.14.45]
LinkDB

KEGG   REACTION: R08653
Entry
R08653                      Reaction                               
Name
(Z)-phenylacetaldehyde-oxime,NADPH:oxygen oxidoreductase (adding cysteine)
Definition
(Z)-Phenylacetaldehyde oxime + L-Cysteine + NADPH + Oxygen + H+ <=> S-(Phenylacetothiohydroximoyl)-L-cysteine + NADP+ + 2 H2O
Equation
C16075 + C00097 + C00005 + C00007 + C00080 <=> C17237 + C00006 + 2 C00001
Comment
multi-step reaction (similar to R08168, R08607+R08608)
Reaction class
RC00001  C00005_C00006
RC01705  C00097_C17237
RC02210  C16075_C17237
Enzyme
1.14.-.-
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.-  Acting on paired donors, with incorporation or reduction of molecular oxygen
    1.14.-.-
     R08653  (Z)-Phenylacetaldehyde oxime + L-Cysteine + NADPH + Oxygen + H+ <=> S-(Phenylacetothiohydroximoyl)-L-cysteine + NADP+ + 2 H2O
Orthology
K11818  aromatic aldoxime N-monooxygenase [EC:1.14.14.45]
LinkDB

KEGG   REACTION: R10671
Entry
R10671                      Reaction                               
Name
L-tyrosine,[reduced NADPH-hemoprotein reductase]:oxygen oxidoreductase (N-hydroxylating)
Definition
L-Tyrosine + 2 Oxygen + 2 [Reduced NADPH---hemoprotein reductase] <=> (E)-4-Hydroxyphenylacetaldehyde oxime + 2 [Oxidized NADPH---hemoprotein reductase] + 3 H2O + CO2
Equation
C00082 + 2 C00007 + 2 C03024 <=> C04350 + 2 C03161 + 3 C00001 + C00011
Comment
three-step reaction (see R00730+R04460+R07190, similar to R09578, R09579+R09580+R09581)
Reaction class
RC02295  C00082_C04350
Enzyme
1.14.14.36
Pathway
rn00966  Glucosinolate biosynthesis
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.36
     R10671  L-Tyrosine + 2 Oxygen + 2 [Reduced NADPH---hemoprotein reductase] <=> (E)-4-Hydroxyphenylacetaldehyde oxime + 2 [Oxidized NADPH---hemoprotein reductase] + 3 H2O + CO2
Orthology
K13027  tyrosine N-monooxygenase [EC:1.14.14.36]
Other DBs
RHEA: 32314
LinkDB

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