Entry |
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Definition |
4-(1-Methyl-2-pyrrolidinyl)-3-oxobutanoate + 1-Methylpyrrolinium <=> Cuscohygrine + CO2 + H+
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Equation |
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Comment |
nonenzymatic decarboxylative condensation
multi-step reaction
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Pathway |
rn00960 | Tropane, piperidine and pyridine alkaloid biosynthesis |
rn01110 | Biosynthesis of secondary metabolites |
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Reference |
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Authors |
Bedewitz MA, Jones AD, D'Auria JC, Barry CS. |
Title |
Tropinone synthesis via an atypical polyketide synthase and P450-mediated cyclization. |
Journal |
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LinkDB |
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