REACTION: R08923
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Entry
R08923 Reaction
Name
(+)-pulegone,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (9-hydroxylating)
Definition
Pulegone + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (+)-Menthofuran + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C09893
+
C03024
+
C00007
<=>
C18025
+
C03161
+ 2
C00001
Comment
multi-step reaction (9-hydroxylation, cyclization and dehydration)
Reaction class
RC02978
C09893_C18025
Enzyme
1.14.14.143
Pathway
rn00902
Monoterpenoid biosynthesis
rn01110
Biosynthesis of secondary metabolites
Orthology
K15093
(+)-menthofuran synthase [EC:
1.14.14.143
]
Other DBs
RHEA:
25661
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