KEGG   REACTION: R09694
Entry
R09694                      Reaction                               
Name
1,5-anhydro-D-fructose hydro-lyase (ascopyrone-M-forming)
Definition
1,5-Anhydro-D-fructose <=> 1,5-Anhydro-4-deoxy-D-glycero-hex-3-en-2-ulose + H2O
Equation
C06485 <=> C19822 + C00001
Comment
the first step of two-step reaction (see R09696, R09694+R09695)
Reaction class
RC01448  C06485_C19822
Enzyme
4.2.1.110       4.2.1.111
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.2  Carbon-oxygen lyases
   4.2.1  Hydro-lyases
    4.2.1.110
     R09694  1,5-Anhydro-D-fructose <=> 1,5-Anhydro-4-deoxy-D-glycero-hex-3-en-2-ulose + H2O
    4.2.1.111
     R09694  1,5-Anhydro-D-fructose <=> 1,5-Anhydro-4-deoxy-D-glycero-hex-3-en-2-ulose + H2O
Other DBs
RHEA: 15728
LinkDB

KEGG   REACTION: R09695
Entry
R09695                      Reaction                               
Definition
1,5-Anhydro-4-deoxy-D-glycero-hex-3-en-2-ulose <=> 2-Hydroxy-2-(hydroxymethyl)-2H-pyran-3(6H)-one
Equation
C19822 <=> C19821
Comment
the second step of two-step reaction (see R09696, R09694+R09695)
Reaction class
RC02607  C19821_C19822
Enzyme
4.2.1.110
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.2  Carbon-oxygen lyases
   4.2.1  Hydro-lyases
    4.2.1.110
     R09695  1,5-Anhydro-4-deoxy-D-glycero-hex-3-en-2-ulose <=> 2-Hydroxy-2-(hydroxymethyl)-2H-pyran-3(6H)-one
Other DBs
RHEA: 13748
LinkDB

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