KEGG   REACTION: R10041
Entry
R10041                      Reaction                               
Definition
(E)-Phenylacetaldoxime <=> (Z)-Phenylacetaldehyde oxime
Equation
C19714 <=> C16075
Comment
spontaneous
the first step of three-step reaction (see R11732, R10041+R07638+R11733)
Reaction class
RC01159  C16075_C19714
Enzyme
1.14.14.44
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.44
     R10041  (E)-Phenylacetaldoxime <=> (Z)-Phenylacetaldehyde oxime
Orthology
K00495  phenylacetaldehyde oxime monooxygenase [EC:1.14.14.44]
Other DBs
RHEA: 52163
LinkDB

KEGG   REACTION: R07638
Entry
R07638                      Reaction                               
Name
(Z)-phenylacetaldehyde-oxime hydro-lyase
Definition
(Z)-Phenylacetaldehyde oxime <=> Phenylacetonitrile + H2O
Equation
C16075 <=> C16074 + C00001
Comment
the second step of three-step reaction (see R11732, R10041+R07638+R11733)
Reaction class
RC01076  C16074_C16075
Enzyme
1.14.14.44      4.8.1.4
Pathway
rn00460  Cyanoamino acid metabolism
rn00643  Styrene degradation
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.44
     R07638  (Z)-Phenylacetaldehyde oxime <=> Phenylacetonitrile + H2O
 4. Lyase reactions
  4.8  Nitrogen-oxygen lyases
   4.8.1  Hydro-lyases
    4.8.1.4
     R07638  (Z)-Phenylacetaldehyde oxime <=> Phenylacetonitrile + H2O
Orthology
K00495  phenylacetaldehyde oxime monooxygenase [EC:1.14.14.44]
K10566  phenylacetaldoxime dehydratase [EC:4.8.1.4]
Other DBs
RHEA: 20072
LinkDB

KEGG   REACTION: R11733
Entry
R11733                      Reaction                               
Name
phenylacetonitrile,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase [(R)-mandelonitrile-forming]
Definition
Phenylacetonitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Mandelonitrile + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C16074 + C03024 + C00007 <=> C00561 + C03161 + C00001
Comment
the last step of three-step reaction (see R11732, R10041+R07638+R11733)
Reaction class
RC02540  C00561_C16074
Enzyme
1.14.14.44      1.14.14.77
Pathway
rn00460  Cyanoamino acid metabolism
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.44
     R11733  Phenylacetonitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Mandelonitrile + [Oxidized NADPH---hemoprotein reductase] + H2O
    1.14.14.77
     R11733  Phenylacetonitrile + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Mandelonitrile + [Oxidized NADPH---hemoprotein reductase] + H2O
Orthology
K00495  phenylacetaldehyde oxime monooxygenase [EC:1.14.14.44]
Other DBs
RHEA: 52167
LinkDB

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