KEGG   REACTION: R10185
Entry
R10185                      Reaction                               
Name
ATP:methylphosphonate 5-triphosphoribosyltransferase
Definition
ATP + Methylphosphonate <=> alpha-D-Ribose 1-methylphosphonate 5-triphosphate + Adenine
Equation
C00002 + C20396 <=> C20422 + C00147
Reaction class
RC00005  C20396_C20422
RC00063  C00002_C00147
Enzyme
2.7.8.37
Pathway
rn00440  Phosphonate and phosphinate metabolism
rn01100  Metabolic pathways
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.7  Transferring phosphorus-containing groups
   2.7.8  Transferases for other substituted phosphate groups
    2.7.8.37
     R10185  ATP + Methylphosphonate <=> alpha-D-Ribose 1-methylphosphonate 5-triphosphate + Adenine
Orthology
K05780  alpha-D-ribose 1-methylphosphonate 5-triphosphate synthase subunit PhnL [EC:2.7.8.37]
K06164  alpha-D-ribose 1-methylphosphonate 5-triphosphate synthase subunit PhnI [EC:2.7.8.37]
K06165  alpha-D-ribose 1-methylphosphonate 5-triphosphate synthase subunit PhnH [EC:2.7.8.37]
K06166  alpha-D-ribose 1-methylphosphonate 5-triphosphate synthase subunit PhnG [EC:2.7.8.37]
LinkDB

KEGG   REACTION: R10186
Entry
R10186                      Reaction                               
Name
alpha-D-ribose-1-methylphosphonate-5-triphosphate diphosphohydrolase
Definition
alpha-D-Ribose 1-methylphosphonate 5-triphosphate + H2O <=> alpha-D-Ribose 1-methylphosphonate 5-phosphate + Diphosphate
Equation
C20422 + C00001 <=> C20423 + C00013
Reaction class
RC00002  C20422_C20423
Enzyme
3.6.1.63
Pathway
rn00440  Phosphonate and phosphinate metabolism
rn01100  Metabolic pathways
Brite
Enzymatic reactions [BR:br08201]
 3. Hydrolase reactions
  3.6  Acting on acid anhydrides
   3.6.1  In phosphorus-containing anhydrides
    3.6.1.63
     R10186  alpha-D-Ribose 1-methylphosphonate 5-triphosphate + H2O <=> alpha-D-Ribose 1-methylphosphonate 5-phosphate + Diphosphate
Orthology
K06162  alpha-D-ribose 1-methylphosphonate 5-triphosphate diphosphatase [EC:3.6.1.63]
LinkDB

KEGG   REACTION: R10204
Entry
R10204                      Reaction                               
Name
alpha-D-ribose-1-methylphosphonate-5-phosphate C-P-lyase (methane forming)
Definition
alpha-D-Ribose 1-methylphosphonate 5-phosphate + S-Adenosyl-L-methionine + Reduced acceptor <=> alpha-D-Ribose 1,2-cyclic phosphate 5-phosphate + Methane + L-Methionine + 5'-Deoxyadenosine + Acceptor
Equation
C20423 + C00019 + C00030 <=> C20440 + C01438 + C00073 + C05198 + C00028
Reaction class
RC03078  C20423_C20440
RC03079  C01438_C20423
Enzyme
4.7.1.1
Pathway
rn00440  Phosphonate and phosphinate metabolism
rn01100  Metabolic pathways
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.7  carbon-phosphorus lyases
   4.7.1  carbon-phosphorus lyases (only sub-subclass identified to date)
    4.7.1.1
     R10204  alpha-D-Ribose 1-methylphosphonate 5-phosphate + S-Adenosyl-L-methionine + Reduced acceptor <=> alpha-D-Ribose 1,2-cyclic phosphate 5-phosphate + Methane + L-Methionine + 5'-Deoxyadenosine + Acceptor
Orthology
K06163  alpha-D-ribose 1-methylphosphonate 5-phosphate C-P lyase [EC:4.7.1.1]
Other DBs
RHEA: 34710
LinkDB

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