KEGG   REACTION: R11450
Entry
R11450                      Reaction                               
Name
eicosanoyl-CoA:methylmalonyl-CoA C-acyltransferase (mycocerosate-forming)
Definition
Eicosanoyl-CoA + 4 Methylmalonyl-CoA + 8 NADPH + 8 H+ + Acyl-carrier protein <=> C32-Mycocerosyl-[acp] + 5 CoA + 4 CO2 + 8 NADP+ + 4 H2O
Equation
C02041 + 4 C02557 + 8 C00005 + 8 C00080 + C00229 <=> C21393 + 5 C00010 + 4 C00011 + 8 C00006 + 4 C00001
Comment
Acy-carrier protein is acp domain of the enzyme itself [KO:K11628].
Reaction class
RC00039  C00229_C21393
RC03439  C02041_C21393
Enzyme
2.3.1.111
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.1  Transferring groups other than aminoacyl groups
    2.3.1.111
     R11450  Eicosanoyl-CoA + 4 Methylmalonyl-CoA + 8 NADPH + 8 H+ + Acyl-carrier protein <=> C32-Mycocerosyl-[acp] + 5 CoA + 4 CO2 + 8 NADP+ + 4 H2O
Orthology
K11628  mycocerosic acid synthase [EC:2.3.1.111]
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