KEGG   REACTION: R12227
Entry
R12227                      Reaction                               
Name
(S)-beta-macrocarpene,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
(S)-beta-Macrocarpene + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> [(4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)-cyclohex-1-en-1-yl]methanol + H2O + [Oxidized NADPH---hemoprotein reductase]
Equation
C19752 + C00007 + C03024 <=> C22012 + C00001 + C03161
Comment
the first step of three-step reaction (see R12226, R12227+R12228+R12229)
Reaction class
RC00724  C19752_C22012
Enzyme
1.14.14.160
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.160
     R12227  (S)-beta-Macrocarpene + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> [(4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)-cyclohex-1-en-1-yl]methanol + H2O + [Oxidized NADPH---hemoprotein reductase]
LinkDB

KEGG   REACTION: R12228
Entry
R12228                      Reaction                               
Name
[(4S)-4-(5,5-dimethylcyclohex-1-en-1-yl)-cyclohex-1-en-1-yl]methanol,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
[(4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)-cyclohex-1-en-1-yl]methanol + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> (4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)cyclohex-1-ene-1-carbaldehyde + 2 H2O + [Oxidized NADPH---hemoprotein reductase]
Equation
C22012 + C00007 + C03024 <=> C22013 + 2 C00001 + C03161
Comment
the second step of three-step reaction (see R12226, R12227+R12228+R12229)
Reaction class
RC01033  C22012_C22013
Enzyme
1.14.14.160
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.160
     R12228  [(4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)-cyclohex-1-en-1-yl]methanol + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> (4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)cyclohex-1-ene-1-carbaldehyde + 2 H2O + [Oxidized NADPH---hemoprotein reductase]
LinkDB

KEGG   REACTION: R12229
Entry
R12229                      Reaction                               
Name
(4S)-4-(5,5-dimethylcyclohex-1-en-1-yl)cyclohex-1-ene-1-carbaldehyde,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
(4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)cyclohex-1-ene-1-carbaldehyde + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> Zealexin A1 + H2O + [Oxidized NADPH---hemoprotein reductase]
Equation
C22013 + C00007 + C03024 <=> C22011 + C00001 + C03161
Comment
the last step of three-step reaction (see R12226, R12227+R12228+R12229)
Reaction class
RC01500  C22011_C22013
Enzyme
1.14.14.160
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.160
     R12229  (4S)-4-(5,5-Dimethylcyclohex-1-en-1-yl)cyclohex-1-ene-1-carbaldehyde + Oxygen + [Reduced NADPH---hemoprotein reductase] <=> Zealexin A1 + H2O + [Oxidized NADPH---hemoprotein reductase]
LinkDB

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