KEGG   REACTION: R12289
Entry
R12289                      Reaction                               
Definition
Medium-chain 3-oxoacyl-[acyl-carrier protein] + Glycerone phosphate <=> 2-Oxo-3-(phosphooxy)propyl 3-oxoalkanoate + Acyl-carrier protein
Equation
C22064 + C00111 <=> C22065 + C00229
Comment
the first step of two-step reaction (see R13418, R12289+R13419)
Reaction class
RC00039  C00229_C22064
RC00041  C00111_C22065
Enzyme
2.3.1.277
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.1  Transferring groups other than aminoacyl groups
    2.3.1.277
     R12289  Medium-chain 3-oxoacyl-[acyl-carrier protein] + Glycerone phosphate <=> 2-Oxo-3-(phosphooxy)propyl 3-oxoalkanoate + Acyl-carrier protein
Other DBs
RHEA: 56863
LinkDB

KEGG   REACTION: R13419
Entry
R13419                      Reaction                               
Definition
2-Oxo-3-(phosphooxy)propyl 3-oxoalkanoate <=> (4-Alkanoyl-5-oxo-2,5-dihydrofuran-3-yl)methyl phosphate + H2O
Equation
C22065 <=> C21774 + C00001
Comment
spontaneous
the second step of two-step reaction (see R13418, R12289+R13419)
Enzyme
2.3.1.277
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.1  Transferring groups other than aminoacyl groups
    2.3.1.277
     R13419  2-Oxo-3-(phosphooxy)propyl 3-oxoalkanoate <=> (4-Alkanoyl-5-oxo-2,5-dihydrofuran-3-yl)methyl phosphate + H2O
LinkDB

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