KEGG   REACTION: R13285
Entry
R13285                      Reaction                               
Name
4-oxocyclohexane-1-carboxylate:oxygen oxidoreductase (4-oxocyclohex-2-ene-1-carboxylate-forming)
Definition
4-Oxocyclohexanecarboxylate + Oxygen <=> 4-Oxocyclohex-2-ene-1-carboxylate + Hydrogen peroxide
Equation
Reaction class
RC00921  C03767_C22887
Enzyme
Pathway
rn00362  Benzoate degradation
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.17  Acting on CH or CH2 groups
   1.17.3  With oxygen as acceptor
    1.17.3.5
     R13285  4-Oxocyclohexanecarboxylate + Oxygen <=> 4-Oxocyclohex-2-ene-1-carboxylate + Hydrogen peroxide
Orthology
K27500  4-oxocyclohexanecarboxylate 2-dehydrogenase [EC:1.17.3.5]
Reference
1  [PMID:34583900]
  Authors
Yamamoto T, Hasegawa Y, Lau PCK, Iwaki H
  Title
Identification and characterization of a chc gene cluster responsible for the aromatization pathway of cyclohexanecarboxylate degradation in Sinomonas cyclohexanicum ATCC 51369.
  Journal
J Biosci Bioeng 132:621-629 (2021)
DOI:10.1016/j.jbiosc.2021.08.013
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