REACTION: R13376
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Entry
R13376 Reaction
Definition
Dihydroprecondylocarpine acetate <=> Dehydrosecodine + Acetate
Equation
C22935
<=>
C22960
+
C00033
Comment
spontaneous
Enzyme
1.3.1.128
Pathway
rn00901
Indole alkaloid biosynthesis
rn01100
Metabolic pathways
rn01110
Biosynthesis of secondary metabolites
Module
M00965
Vinblastine biosynthesis, geissoschizine => vinblastine
Brite
Enzymatic reactions [BR:
br08201
]
1. Oxidoreductase reactions
1.3 Acting on the CH-CH group of donors
1.3.1 With NAD+ or NADP+ as acceptor
1.3.1.128
R13376 Dihydroprecondylocarpine acetate <=> Dehydrosecodine + Acetate
BRITE hierarchy
Reference
1 [PMID:
38319969
]
Authors
DeMars MD 2nd, O'Connor SE.
Title
Evolution and diversification of carboxylesterase-like [4+2] cyclases in aspidosperma and iboga alkaloid biosynthesis.
Journal
Proc Natl Acad Sci U S A 121:e2318586121 (2024)
DOI:
10.1073/pnas.2318586121
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