KEGG   COMPOUND: C15685
Entry
C15685                      Compound                               
Name
Protomycinolide IV
Formula
C21H32O4
Exact mass
348.2301
Mol weight
348.48
Structure
Sequence
0 Mtk  1 Mtd  2 Mad  3 Man  4 Mte  5 Mtk  6 Mtd  7 Man
  Gene
0-2 mycAI [UP:Q83WF0]; 3 mycAII [UP:Q83WE9]; 4-5 mycAIII
[UP:Q83WE8]; 6 mycAIV [UP:Q83WE7]; 7 mycAV [UP:Q83WE6]
  Organism
Micromonospora griseorubida
  Type
PK
Reaction
R10876 R12660
Pathway
map00522  Biosynthesis of 12-, 14- and 16-membered macrolides
map01100  Metabolic pathways
map01110  Biosynthesis of secondary metabolites
Module
M00934  Mycinamicin biosynthesis, malonyl-CoA + methylmalonyl-CoA => protomycinolide IV => mycinamicin II
Enzyme
2.4.1.-
Brite
Lipids [BR:br08002]
 PK  Polyketides
  PK04 Macrolides and lactone polyketides
   C15685  Protomycinolide IV
Other DBs
CAS: 79495-87-7
PubChem: 47205011
ChEBI: 80021
NIKKAJI: J923.967G
LinkDB
KCF data

ATOM        25
            1   C2x C    16.1700  -19.1100
            2   C1y C    16.1700  -20.5100
            3   C1y C    17.3600  -21.2100
            4   O7x O    18.6200  -20.5100
            5   C2x C    17.3600  -18.4100
            6   C2x C    18.6200  -16.3100
            7   C2x C    17.3600  -17.0100
            8   C1y C    21.0000  -16.3100
            9   C1x C    21.0000  -14.9100
            10  C1y C    19.8100  -14.2100
            11  C5x C    18.6200  -14.9100
            12  C2x C    21.0000  -19.1100
            13  C1y C    22.2600  -18.4100
            14  C1y C    22.2600  -17.0100
            15  C7x C    19.8100  -21.2100
            16  C2x C    21.0000  -20.5100
            17  O5x O    17.4300  -14.2100
            18  C1b C    17.3600  -22.6800
            19  C1a C    16.1700  -23.3800
            20  O6a O    19.8100  -22.6800
            21  C1a C    23.3800  -19.1100
            22  C1a C    19.8100  -17.0100
            23  C1a C    19.8100  -12.8100
            24  C1a C    14.9800  -21.2100
            25  O1a O    23.3800  -16.3100
BOND        25
            1     1   2 1
            2     2   3 1
            3     3   4 1
            4     1   5 2
            5     6   7 2
            6     5   7 1
            7     8   9 1
            8     9  10 1
            9    10  11 1
            10    6  11 1
            11   12  13 1
            12   13  14 1
            13   14   8 1
            14    4  15 1
            15   15  16 1
            16   12  16 2
            17   11  17 2
            18    3  18 1 #Down
            19   18  19 1
            20   15  20 2
            21   13  21 1 #Up
            22    8  22 1 #Up
            23   10  23 1 #Down
            24    2  24 1 #Up
            25   14  25 1 #Down

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