KEGG   REACTION: R01544
Entry
R01544                      Reaction                               
Name
2-amino-2-deoxy-D-gluconate ammonia-lyase (isomerizing; 2-dehydro-3-deoxy-D-gluconate-forming)
Definition
2-Amino-2-deoxy-D-gluconate <=> 2-Dehydro-3-deoxy-D-gluconate + Ammonia
Equation
C03752 <=> C00204 + C00014
Comment
PLP-dependent enzyme (see R10773+R10774+R10775)
Reaction class
RC00544  C00204_C03752
Enzyme
4.3.1.9
Pathway
rn00030  Pentose phosphate pathway
rn01100  Metabolic pathways
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.3  Carbon-nitrogen lyases
   4.3.1  Ammonia-lyases
    4.3.1.9
     R01544  2-Amino-2-deoxy-D-gluconate <=> 2-Dehydro-3-deoxy-D-gluconate + Ammonia
Orthology
K22345  glucosaminate ammonia-lyase [EC:4.3.1.9]
Other DBs
RHEA: 12491
LinkDB

KEGG   REACTION: R10773
Entry
R10773                      Reaction                               
Definition
2-Amino-2-deoxy-D-gluconate <=> (2Z,4S,5R)-2-Amino-4,5,6-trihydroxyhex-2-enoate + H2O
Equation
C03752 <=> C20844 + C00001
Comment
PLP-dependent enzyme (see R01544, R10773+R10774+R10775)
Reaction class
RC03273  C03752_C20844
Enzyme
4.3.1.9
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.3  Carbon-nitrogen lyases
   4.3.1  Ammonia-lyases
    4.3.1.9
     R10773  2-Amino-2-deoxy-D-gluconate <=> (2Z,4S,5R)-2-Amino-4,5,6-trihydroxyhex-2-enoate + H2O
Other DBs
RHEA: 49539
LinkDB

KEGG   REACTION: R10774
Entry
R10774                      Reaction                               
Definition
(2Z,4S,5R)-2-Amino-4,5,6-trihydroxyhex-2-enoate <=> (4S,5R)-4,5,6-Trihydroxy-2-iminohexanoate
Equation
C20844 <=> C20845
Comment
PLP-dependent enzyme (see R01544, R10773+R10774+R10775)
Reaction class
RC03274  C20844_C20845
Enzyme
4.3.1.9
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.3  Carbon-nitrogen lyases
   4.3.1  Ammonia-lyases
    4.3.1.9
     R10774  (2Z,4S,5R)-2-Amino-4,5,6-trihydroxyhex-2-enoate <=> (4S,5R)-4,5,6-Trihydroxy-2-iminohexanoate
Other DBs
RHEA: 49543
LinkDB

KEGG   REACTION: R10775
Entry
R10775                      Reaction                               
Definition
(4S,5R)-4,5,6-Trihydroxy-2-iminohexanoate + H2O <=> 2-Dehydro-3-deoxy-D-gluconate + Ammonia
Equation
C20845 + C00001 <=> C00204 + C00014
Comment
PLP-dependent enzyme (see R01544, R10773+R10774+R10775)
Reaction class
RC03275  C00204_C20845
Enzyme
4.3.1.9
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.3  Carbon-nitrogen lyases
   4.3.1  Ammonia-lyases
    4.3.1.9
     R10775  (4S,5R)-4,5,6-Trihydroxy-2-iminohexanoate + H2O <=> 2-Dehydro-3-deoxy-D-gluconate + Ammonia
Other DBs
RHEA: 49547
LinkDB

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